Saturn's moon Enceladus emits plumes of water vapour and ice particles from fractures near its south pole, suggesting the possibility of a subsurface ocean. These plume particles are the dominant source of Saturn's E ring. A previous in situ analysis of these particles concluded that the minor organic or siliceous components, identified in many ice grains, could be evidence for interaction between Enceladus' rocky core and liquid water. It was not clear, however, whether the liquid is still present today or whether it has frozen. Here we report the identification of a population of E-ring grains that are rich in sodium salts ( approximately 0.5-2% by mass), which can arise only if the plumes originate from liquid water. The abundance of various salt components in these particles, as well as the inferred basic pH, exhibit a compelling similarity to the predicted composition of a subsurface Enceladus ocean in contact with its rock core. The plume vapour is expected to be free of atomic sodium. Thus, the absence of sodium from optical spectra is in good agreement with our results. In the E ring the upper limit for spectroscopy is insufficiently sensitive to detect the concentrations we found.

The discovery of a plume of water vapour and ice particles emerging from warm fractures ('tiger stripes') in Saturn's small, icy moon Enceladus raised the question of whether the plume emerges from a subsurface liquid source or from the decomposition of ice. Previous compositional analyses of particles injected by the plume into Saturn's diffuse E ring have already indicated the presence of liquid water, but the mechanisms driving the plume emission are still debated. Here we report an analysis of the composition of freshly ejected particles close to the sources. Salt-rich ice particles are found to dominate the total mass flux of ejected solids (more than 99 per cent) but they are depleted in the population escaping into Saturn's E ring. Ice grains containing organic compounds are found to be more abundant in dense parts of the plume. Whereas previous Cassini observations were compatible with a variety of plume formation mechanisms, these data eliminate or severely constrain non-liquid models and strongly imply that a salt-water reservoir with a large evaporating surface provides nearly all of the matter in the plume.

Detection of sodium-salt-rich ice grains emitted from the plume of the Saturnian moon Enceladus suggests that the grains formed as frozen droplets from a liquid water reservoir that is, or has been, in contact with rock. Gravitational field measurements suggest a regional south polar subsurface ocean of about 10 kilometres thickness located beneath an ice crust 30 to 40 kilometres thick. These findings imply rock-water interactions in regions surrounding the core of Enceladus. The resulting chemical 'footprints' are expected to be preserved in the liquid and subsequently transported upwards to the near-surface plume sources, where they eventually would be ejected and could be measured by a spacecraft. Here we report an analysis of silicon-rich, nanometre-sized dust particles (so-called stream particles) that stand out from the water-ice-dominated objects characteristic of Saturn. We interpret these grains as nanometre-sized SiO2 (silica) particles, initially embedded in icy grains emitted from Enceladus' subsurface waters and released by sputter erosion in Saturn's E ring. The composition and the limited size range (2 to 8 nanometres in radius) of stream particles indicate ongoing high-temperature (>90 °C) hydrothermal reactions associated with global-scale geothermal activity that quickly transports hydrothermal products from the ocean floor at a depth of at least 40 kilometres up to the plume of Enceladus.

Saturn's moon Enceladus harbours a global water ocean , which lies under an ice crust and above a rocky core . Through warm cracks in the crust a cryo-volcanic plume ejects ice grains and vapour into space that contain materials originating from the ocean. Hydrothermal activity is suspected to occur deep inside the porous core, powered by tidal dissipation . So far, only simple organic compounds with molecular masses mostly below 50 atomic mass units have been observed in plume material. Here we report observations of emitted ice grains containing concentrated and complex macromolecular organic material with molecular masses above 200 atomic mass units. The data constrain the macromolecular structure of organics detected in the ice grains and suggest the presence of a thin organic-rich film on top of the oceanic water table, where organic nucleation cores generated by the bursting of bubbles allow the probing of Enceladus' organic inventory in enhanced concentrations.

The Cassini-Huygens Cosmic Dust Analyzer (CDA) is intended to provide direct observations of dust grains with masses between 10 −19 and 10 −9 kg in interplanetary space and in the jovian and saturnian systems, to investigate their physical, chemical and dynamical properties as functions of the distances to the Sun, to Jupiter and to Saturn and its satellites and rings, to study their interaction with the saturnian rings, satellites and magnetosphere. Chemical composition of interplanetary meteoroids will be compared with asteroidal and cometary dust, as well as with Saturn dust, ejecta

During Cassini's close flyby of Enceladus on 14 July 2005, the High Rate Detector of the Cosmic Dust Analyzer registered micron-sized dust particles enveloping this satellite. The dust impact rate peaked about 1 minute before the closest approach of the spacecraft to the moon. This asymmetric signature is consistent with a locally enhanced dust production in the south polar region of Enceladus. Other Cassini experiments revealed evidence for geophysical activities near Enceladus' south pole: a high surface temperature and a release of water gas. Production or release of dust particles related to these processes may provide the dominant source of Saturn's E ring

Interplanetary dust particles hit the surfaces of airless bodies in the Solar System, generating charged and neutral gas clouds, as well as secondary ejecta dust particles. Gravitationally bound ejecta clouds that form dust exospheres were recognized by in situ dust instruments around the icy moons of Jupiter and Saturn, but have hitherto not been observed near bodies with refractory regolith surfaces. High-altitude Apollo 15 and 17 observations of a 'horizon glow' indicated a putative population of high-density small dust particles near the lunar terminators, although later orbital observations yielded upper limits on the abundance of such particles that were a factor of about 10(4) lower than that necessary to produce the Apollo results. Here we report observations of a permanent, asymmetric dust cloud around the Moon, caused by impacts of high-speed cometary dust particles on eccentric orbits, as opposed to particles of asteroidal origin following near-circular paths striking the Moon at lower speeds. The density of the lunar ejecta cloud increases during the annual meteor showers, especially the Geminids, because the lunar surface is exposed to the same stream of interplanetary dust particles. We expect all airless planetary objects to be immersed in similar tenuous clouds of dust.

Saturn’s moon Enceladus is erupting a plume of gas and ice grains from its south pole. Linked directly to the moon’s subsurface global ocean, plume material travels through cracks in the icy crust and is ejected into space. The subsurface ocean is believed to be in contact with the rocky core, with ongoing hydrothermal activity present. The Cassini spacecraft’s Ion and Neutral Mass Spectrometer (INMS) detected volatile, gas phase, organic species in the plume and the Cosmic Dust Analyser (CDA) discovered high-mass, complex organic material in a small fraction of ice grains. Here, we present a broader compositional analysis of CDA mass spectra from organic-bearing ice grains. Through analogue experiments, we find spectral characteristics attributable to low-mass organic compounds in the Enceladean ice grains: nitrogen-bearing, oxygen-bearing, and aromatic. By comparison with INMS results, we identify low-mass amines [particularly (di)methylamine and/or ethylamine] and carbonyls (with acetic acid and/or acetaldehyde most suitable) as the best candidates for the N- and O-bearing compounds, respectively. Inferred organic concentrations in individual ice particles vary but may reach tens of mmol levels. The low-mass nitrogen- and oxygen-bearing compounds are dissolved in the ocean, evaporating efficiently at its surface and entering the ice grains via vapour adsorption. The potentially partially water soluble, low-mass aromatic compounds may alternatively enter ice grains via aerosolization. These amines, carbonyls, and aromatic compounds could be ideal precursors for mineral-catalysed Friedel–Crafts hydrothermal synthesis of biologically relevant organic compounds in the warm depths of Enceladus’ ocean.