Nanoparticles containing metals in their structure constitute an increasingly large group of substances present in the air. They come from both natural and anthropogenic sources. The wider and wider use...
This paper discusses an environmental criterion rarely addressed in the literature for the selection of salt hydrates for use in photovoltaic installations as Phase change materials. The aim of the paper is to assess the possibility of utilization of used salt hydrates from photovoltaic installations according to current Polish legal requirements concerning the environment. The properties of the composition components of hydrated salts were discussed in terms of their safety for the environment before and after the period of exploitation in photovoltaic panels. A method of dealing with used salt hydrates was proposed and a waste code was assigned. It has been established that spent salt hydrates will be allowed to be collected in no-outflow tanks and accepted at liquid waste collection points, which operate at water supply and sewerage companies, and the load of permissible pollutants should not exceed the value for industrial sewage.
Sewage sludge from sewage treatment plants has soil-forming and fertilising properties. However, sewage sludge cannot always be used in nature, including agriculture. One of the main reasons is the concentration of heavy metals. Sludge from wastewater treatment plants operating in MBR (membrane biological reactor) and SBR (sequential batch reactor) systems was analysed. Studies comparing the risk analysis of the natural use of sludge from MBR and SBR treatment plants were performed for the first time, due to the fact that more and more MBR plants, which are a BAT technology, are being developed in Poland, displacing the classical SBR plants. MBR technology uses a combination of activated sludge and filtration with microfiltration membranes. Wastewater treated in these reactors meets the highest quality standards, both in terms of physicochemical and microbiological aspects. This paper presents studies on the mobility of heavy metals in sewage sludge carried out using the BCR sequential extraction method. Geo-accumulation index (GAI), potential environmental risk index (ER), risk assessment code (RAC), and environmental risk determinant (ERD) were calculated. Heavy metals dominated the stable fractions in all cases. Furthermore, an increased content of copper and cadmium was observed in the MBR sludge. This fact is favourable in view of the efforts to eliminate heavy metals in the environment.
Electrical cables are a potential source of ignition and fire hazards in various types of buildings and industrial installations, as well as in all modes of transportation, including aircraft. Fires in buildings pose the greatest threat to human life and health. The composition of thermal degradation products depends mainly on the type of combustible materials and the type of combustion process—flaming or smoldering. The purpose of this paper was to determine, based on experimental studies, the effects of flaming and smoldering combustion on the response times of fire smoke detectors. In addition, the concentrations of fire gases formed in the process of duct combustion, including CO, SO2, NO2, NO, HCN, HCl, HBr and HF, were measured using an FTIR spectrometer. The results presented confirm the significant effect of the way the cable samples burned on detector tripping time. The highest concentration of smoke (Y) in the test chamber was obtained during flame combustion. It was further found that the characteristics of the cable insulation material used, such as the type of PVC, had a significant effect on the toxicity of the emitted gases. The largest amounts of toxic gases were emitted during the smoldering combustion of a cable with a plasticized PVC sheath.
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