Two-phase composites consisting of LaPO 4 or CePO 4 and alumina, mullite, or zirconia were found to be machinable; i.e., they can be cut and drilled using conventional tungsten carbide metal-working tools. Single-phase LaPO 4 was also machinable. Measurements of drilling rates, grinding rates, and normal forces are used to compare the ease of machining in these materials and in a conventional machinable glass-ceramic material, and to provide preliminary information on the relation between microstructure and machining properties. In Hertzian contact experiments these materials showed extensive nonlinear behavior associated with a damage zone beneath the contact site, similar to other machinable ceramics. Mechanisms of material removal are discussed.
We give a simple theoretical analysis of the dynamics of an arbitrary atom in a general harmonic solid. The atom under discussion may be an impurity. Several general results are found which limit the possible temperature dependences of the mean-square displacement and mean-square velocity in a way which is described. These results are expected to be most useful in analyzing experiments involving Debye-Wallerfactor and Mossbauer-thermal-shift measurements. As an illustration the allowed range of mean-square displacements at T = 0 and r = 80°K corresponding to a measured value at JT = 298°K is given. These results also provide strong consistency relations that experimental data or numerical calculations should satisfy. One especially interesting result indicates a possible method for determining a simple sum over atomic force constants from Debye-Waller-factor measurements. This sum, which in general is not obtainable from any other type of measurements, could be used as a convenient check on atomic-force-constant models. The dependence of the mean-square displacement and mean-square velocity on the various masses and force constants in the lattice is described. The relation between our results derived in the harmonic approximation and experimentally measurable quantities is discussed. Finally, several experiments which appear to be interesting are mentioned.
Using available data from the literature, we formulate an outline of the major physical and chemical effects expected during solar wind bombardment of the lunar regolith. In agreement with the results of Auger and e.s.c.a. analyses of the composition of lunar grain surfaces, this outline predicts that solar wind sputtering will tend to clean exposed grain surfaces by ejecting material at velocities exceeding lunar escape velocity. We also discuss results showing that Fe is partially reduced in the outer few 10 nm of grain surfaces and that this reduced Fe forms 10 nm diameter range metal spheres throughout the glass during agglutinate formation by micrometeorite impacts. These metal spheres give the agglutinates their distinctive optical and magnetic properties and are partially responsible for the decreasing albedo of the lunar surface with exposure age.
An unusually diverse array of 25 secondary Te oxysalt minerals has been documented from Otto Mountain, California, and 18 of these from the Bird Nest drift sublocality. A paragenetic sequence for these minerals is proposed, using observed overgrowth relationships plus spatial association data and data from other localities. Apart from Te and O, the components Pb, Cu and H are essential in the majority of the minerals. The atomic Cu/Te ratio decreases through the paragenetic sequence. This, and the occurrence of minerals with additional components such as Cl − , CO For the minerals with known crystal structures, two alternative 'structural units' were identified, one consisting only of the Te 4+ or Te 6+ oxyanion, while the other also included small, strongly-bound cations such as Cu 2+ . The degree of polymerization for the Te oxyanion correlated with the paragenetic sequence: the monomeric tellurate anions of early minerals were replaced progressively by dimers, chains and sheet structures, which may relate to a decreasing abundance of the 'network modifying' Cu 2+ cation, analogous to Bowen's discontinuous reaction series in igneous rock-forming silicates.No relationship was seen between paragenetic order and the larger type of structural unit, or structural complexity as defined by information content. This contrasts with results in the literature for evaporite sulfates and pegmatite phosphates. While structure-paragenesis relationships may be widespread, the exact nature of such relationships may be different for different chemical systems and different paragenetic environments.
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