Talc is an insulating layered material that is stable
at ambient
conditions and has high-quality basal cleavage, which is a major advantage
for its use in van der Waals heterostructures. Here, we use near-field
synchrotron infrared nanospectroscopy, Raman spectroscopy, and first-principles
calculations to investigate the structural and vibrational properties
of talc crystals, ranging from monolayer to bulk, in the 300–750
and <60 cm–1 spectral windows. We observe a symmetry
crossover from mono to bilayer talc samples, attributed to the stacking
of adjacent layers. The in-plane lattice parameters and frequencies
of intralayer modes of talc display weak dependence on the number
of layers, consistent with a weak interlayer interaction. On the other
hand, the low-frequency (<60 cm–1) rigid-layer
(interlayer) modes of talc are suitable to identify the number of
layers in ultrathin talc samples, besides revealing strong in-plane
and out-of-plane anisotropy in the interlayer force constants and
related elastic stiffnesses of single crystals. The shear and breathing
force constants of talc are found to be 66 and 28%, respectively,
lower than those of graphite, making talc an excellent lubricant that
can be easily exfoliated. Our results broaden the understanding of
the structural and vibrational properties of talc at the nanoscale
regime and serve as a guide for future ultrathin heterostructures
applications.
Beyond-graphene two-dimensional (2D) materials are envisioned as the future technology for optoelectronics, and the study of group IIIA metal monochalcogenides (GIIIAMMs) in 2D form is an emerging research field. Bulk gallium selenide (GaSe) is a layered material of this family which is widely used in nonlinear optics and is promising as a lubricant. The interlayer coupling in few-layer GaSe is currently unknown, and the stability of different polytypes is unclear. Here we use symmetry arguments and first-principles calculations to investigate the phase stability, interlayer coupling, and the Raman and infrared activity of the low-frequency shear and breathing modes expected in few-layer GaSe. Strategies to distinguish the number of layers and the β and ε polytypes are discussed. These symmetry results are valid for other isostructural few-layer GIIIAMM materials. Most importantly, by using a linear chain model, we show that the shear and breathing force constants reveal an ultra-weak interlayer coupling at the nanoscale in GaSe. These results suggest that β and ε few-layer GaSe show similar lubricant properties to those observed for few-layer graphite. Our analysis opens new perspectives about the study of interlayer interactions and their role in the mechanical and electrical properties of these new 2D materials.
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