Photocatalysis is a promising advanced water treatment technology, and recently the possibility of using hydrogenation to improve the photocatalytic efficiency of titanium dioxide has generated much research interest. Herein we report that the use of high-temperature hydrogenation to prepare black TiO2 primarily results in the formation of bulk defects in the material without affecting its electronic band structure. The hydrogenated TiO2 exhibited significantly worse photocatalytic activity under simulated sunlight compared to the unhydrogenated control, and thus we propose that high-temperature hydrogenation can be counterproductive to improving the photocatalytic activity of TiO2, because of its propensity to form bulk vacancy defects.
The hydrogen desorption properties of commercial nanocrystalline magnesium hydride (Tego
Magnan®
from Degussa–Goldschmidt) processed by controlled mechanical milling
(CMM) are investigated. A profound effect of the powder particle size
on the hydrogen desorption characteristics has been observed. The onset
(TON) and peak hydrogen desorption temperatures measured by differential scanning
calorimetry (DSC) decrease initially slowly with decreasing mean particle size of hydride,
and when the particle size reaches a certain critical threshold value, the desorption
temperatures start decreasing more rapidly with further decrease of particle size. The
total drop of desorption temperature from its initial value for the as-received
MgH2 to the value attained
for the milled MgH2 having a
particle size of ∼500–600 nm is
within the range 40–60 °C. The metastable γ-MgH2
hydride coexists with the stable nanocrystalline
β-MgH2 in the
microstructure of the MgH2
powders ball milled for 10 h and longer. Quantitative evidence shows
that two factors, namely the refined powder particle size and the
γ-MgH2
phase residing within the powder particles, acting additively, are responsible
for a substantial reduction of the hydrogen desorption temperature of
MgH2
hydride.
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