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A new approach to constraining seawater δ34S and sulphate concentration using francolite‐bound sulphate reveals an abrupt increase in δ34S to +50‰ around the Early–Middle Cambrian boundary. Such high δ34S values are best explained by increased rates of pyrite burial due to ocean anoxia coupled with an increased sensitivity of the ocean sulphate reservoir to perturbations due to low sulphate concentrations of 500–700 μgL−1. We argue that the spread of anoxic waters at this time was partly the result of greenhouse warming related to the eruption of the Kalkarindji Large Igneous Province of northern Australia and that it triggered the collapse of early metazoan reef ecosystems during the latest Early Cambrian. Mass extinctions of the last 260 Myr have all coincided with enhanced volcanic activity, while several are also associated with positive shifts in seawater δ34S. Extending this correlation back in time further implicates volcanically induced climate change as a major determining factor in biosphere evolution. Terra Nova, 18, 257–263, 2006

Cyclothemic sedimentary rocks of the Plio-Pleistocene Petane Group outcrop extensively in the Tangoio block of central Hawke's Bay, New Zealand. They are products of inner to mid-shelf sedimentation and were deposited during glacio-eustatic sea level fluctuations along the western margin of a shallow, pericontinental seaway located in a forearc setting. The succession consists of five laterally continuous cyclothems, each containing a fine grained interval of silt and a coarse grained interval of siliciclastic sand gravel or limestone. Five sedimentary facies assemblages comprising 20 separate facies have been recognized. Coarse grained intervals of cyclothems were deposited mostly during relative sea level lowstands and contain up to four facies assemblages: (1) a non-marine assemblage (with three component facies, representing braided river and overbank environments); (2) an estuarine assemblage (with three component facies, representing tidal flat and mud-dominated estuarine environments); (3) a siliciclastic shoreline assemblage (with six component facies, representing greywacke pebble beach, shoreface and inner shelf environments); and (4) a carbonate shelf assemblage (with four component facies, representing tide-dominated, inshore and shallow marine environments). Fine grained intervals of cyclothems were deposited during sea level highstands when the Tangoio area was generally experiencing mid-shelf sedimentation. This produced an offshore assemblage consisting of four component facies. The distribution of facies assemblages during relative sea level lowstands was dependent upon proximity to the shoreline, the type and rate of sediment supply to the basin, and shelf hydrodynamics. Carbonate shelf facies dominate coarse grained intervals in Cyclothems 3-5, but siliciclastic shoreline and non-marine facies dominate in Cyclothems 1 and 2. The abrupt change from siliciclastic to carbonate sedimentation during relative sea level lowstand deposition is thought to have been induced by rapidly falling interglacial to glacial sea level accentuated by regional tectonic shoaling. This caused most of the terrigenous sediment supply to bypass the Tangoio area. Consequently, carbonate sediment accumulated in inshore and shallow marine settings. Facies assemblages rarely show lateral interdigitation, but are vertically stratified over the entire Tangoio block. Facies successions in each cyclothem preserve a record of relative sea level change during deposition of the Petane Group and are consistent with a Plio-Pleistocene sea level change in eastern New Zealand of c. 75-150 m, i.e. approximately the magnitude suggested for Late Quaternary glacio-eustatic sea level changes. North Island. The location of the Tangoio block is indicated by the closed square along section line C-C' (from Cole, 1984). (b) Major geological elements of central Hawke's Bay. Triangles indicate the positions of most of the 102 sections examined in the Tangoio block. (c) Cross-section C-C' showing the position of Plio-Pleistocene strata in the Tang...

U-Pb detrital zircon ages in variably metamorphosed, dominantly fine-

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