Characterizing the detailed compositions of chlorinated paraffins (CPs) commercial mixtures is crucial to understand their environmental sources, fates, and potential risks. In this study, dichloromethane (DCM)-enhanced UPLC-ESI-QTOFMS analysis combined with characteristic isotope chlorine peaks is applied to screen all CPs and their structural analogues in the three most commonly produced CP commercial mixtures (CP-42, CP-52, and CP-70). Mass fractions of total short-chain CPs (SCCPs), medium-chain CPs (MCCPs) and long-chain CPs (LCCPs) ranged from 0.64 to 31.9%, 0.64 to 21.8%, and 0.04 to 43.9%, respectively, in the three commercial mixtures. 113 unsaturated SCCPs, MCCPs, and LCCPs were identified in the commercial mixtures. The detailed mass percentages of saturated and unsaturated CPs with carbon numbers of 10-30, chlorine numbers of 5-28, and unsaturated degrees of 0-7 were characterized in all commercial mixtures. Occurrences of the predominant saturated and unsaturated CPs were further confirmed in air samples collected in Guangdong Province, one of the major CP production areas in China, over one year. The profiles of the detected compounds indicated that LCCPs in air samples might come mainly from the production and usage of CP-52, and unsaturated C-LCCPs were specifically originated from CP-70 used in the area.
There is growing interest in the identification of novel aryl organophosphate triester (OPTE) congeners that may exist in the environment. In this study, we discovered 11 novel aryl OPTEs in north China house dust using a characteristic aryl phosphate fragment-guided high-resolution mass spectrometry method with data-independent acquisition. Tripentylated triphenyl phosphate (TPeTPhP), dicresyl phenyl phosphate (DCrPP), diisodecylphenyl phosphate (DIDPP), butoxyethoxyethyl octyl phenyl phosphate (BEEOPP), dioctyl nonylphenyl phosphate (DONPP), propoxypropyl bis(diphenyl phosphate) (PPBDPhP), octyl nonylphenyl phenyl phosphate (ONPPP), and (saturated mono-oxygen butoxybutyl) butoxyethoxyethyl phenyl phosphate (MBBPP) were detected in 84−100% of 45 samples. ONPPP was present in the highest median concentration of 69.0 ng/g, followed by DONPP (68.7 ng/g), DIDPP (50.3 ng/g), BEEOPP (42.5 ng/g), DCrPP (33.7 ng/g), PPBDPhP (25.0 ng/g), TPeTPhP (9.28 ng/g), and MBBPP (4.80 ng/g). Seven novel aryl OPTEs were also detected in standard house dust SRM2585, and the concentration of DIDPP (4375 ± 660 ng/g) was 4-fold higher than that (1048 ± 44.5 ng/g) of triphenyl phosphate, a typical aryl OPTE. The discovery of these novel OPTEs has significantly enriched our understanding of the aryl OPTEs present in house dust.
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