To have a more comprehensive understanding of the water ecological security status of the Yellow River Basin, this paper constructs a water ecological security evaluation index system founded on the Pressure-State-Response (PSR) model. The indicators are selected by considering factors such as meteorological conditions, population, economy, water resources, water environment, water ecology, land ecology, ecological service functions, pollution control, and capital investment. Then, the “single index quantification-multiple indices syntheses-poly-criteria integration (SMI-P) method was used to determine the water ecological security index (WESI) of 62 cities in the Yellow River Basin, to classify the safety levels, and combined with the spatial autocorrelation analysis to study the regional characteristics. The results prove that: (a) The overall water ecological security of the Yellow River Basin is relatively poor. Half of the 62 cities have reached the second-level warning level, and most of them are concentrated in the upper and middle reaches of the basin. (b) Wetland area is a long-term key factor in the construction of water ecological safety, and the greening rate of built-up areas has an increasing impact on water ecological safety. (c) The overall water ecological security index shows a slow upward trend, with the annual average growth rate was 0.59%. (d) The water ecological security of 62 cities in the Yellow River Basin shows significant spatial autocorrelation. The findings can offer a practical basis for the water ecological management to promote the high-quality development of the Yellow River Basin.
Microplastics are ubiquitous in aquatic environments and interact with other kinds of pollutants, which affects the migration, transformation, and fate of those other pollutants. In this study, we employ carbamazepine (CBZ) as the contaminant to study the influence of polyethylene (PE) microplastics on the adsorption of CBZ pollutants by multiwalled carbon nanotubes (MCNTs) in aqueous solution. The adsorption capacity of CBZ by MCNTs in the presence of PE microplastics was obviously lower than that by MCNTs alone. The influencing factors, including the dose of microplastics, pH, and CBZ solution concentration, on the adsorption of CBZ by MCNTs and MCNTs−PE were thoroughly investigated. The adsorption rate of CBZ by MCNTs decreased from 97.4% to 90.6% as the PE microplastics dose increased from 2 g/L to 20 g/L. This decrease occurred because the MCNTs were coated on the surface of the PE microplastics, which further decreased the effective adsorption area of the MCNTs. This research provides a framework for revealing the effect of microplastics on the adsorption of pollutants by carbon materials in aqueous environments.
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