The integration of organic semiconductors and magnetism has been a fascinating topic for fundamental scientific research and future applications in electronics, because organic semiconductors are expected to possess a large spin-dependent transport length based on weak spin-orbit coupling and weak hyperfine interaction. However, to date, this length has typically been limited to several nanometres at room temperature, and a large length has only been observed at low temperatures. Here we report on a novel organic spin valve device using C 60 as the spacer layer. A magnetoresistance ratio of over 5% was observed at room temperature, which is one of the highest magnetoresistance ratios ever reported. Most importantly, a large spin-dependent transport length of approximately 110 nm was experimentally observed for the C 60 layer at room temperature. These results provide insights for further understanding spin transport in organic semiconductors and may strongly advance the development of spin-based organic devices.
Temperature changes induce self-folding of functionalized graphene into well-defined ultrathin 3D microstructures.
Abstract. Four extreme haze episodes occurred in October 2014 in the North China Plain (NCP). To clarify the formation mechanism of hazes in autumn, strengthened observations were conducted in Beijing from 5 October to 2 November. The meteorological parameters, satellite data, chemical compositions and optical properties of aerosols were obtained. The hazes originated from the NCP, developing in the southwest and northeast directions, with the highest concentration of PM2.5 of 469 μg m−3 in Beijing. The NCP was dominated by a weak high pressure system during the haze episode, which resulted in low surface wind speed and relatively stagnant weather. Moreover, the wind slowed down around Beijing city. The secondary aerosols NO3− was always higher than that of SO42−, which indicated the motor vehicles played a more important part in the hazes in October 2014, even though the oxidation rate from SO2 to SO42− was faster than that of NOx to NO3−. Sudden increases of the concentrations of organic matter, Cl− and BC (black carbon) before each haze episode implied that regional transport of pollutants by biomass burning was important for haze formation during autumn. A satellite map of fire points and the backward trajectories of the air masses also indicated this pollution source. The distinct decrease in the PBL (planetary boundary layer) height during four haze episodes restrained the vertical dispersion of the air pollutants. Water vapor also played a vital role in the formation of hazes by accelerating the chemical transformation of secondary pollutants, leading to hygroscopic growth of aerosols and altering the thermal balance of the atmosphere.
In situ diffusion reflectance infrared Fourier transform spectroscopy was used to study the water adsorption on mineral oxides (SiO 2 , α-Al 2 O 3 , MgO, Fe 2 O 3 , TiO 2 ). The results showed that all the water adsorption isotherms were well fitted with the Brunauer-EmmettTeller (BET)-III type equation, with the calculated monolayers occurring at 24%-30% relative humidity. It showed that about 1-5 layers of water adsorbed on oxides surfaces in ambient relative humidity (20%-90%). The measured deliquescence relative humidity of NaCl was (74 ± 1)%, which demonstrated that DRIFTS is a useful method for the study the hygroscopic behavior of mineral dust. In addition, the limits of DRIFTS were also discussed.
Mixtures of organic compounds with mineral dust are ubiquitous in the atmosphere, whereas the formation pathways and hygroscopic behavior of these mixtures are not well understood. In this study, in situ DRIFTS, XRD, and a vapor sorption analyzer were used to investigate the heterogeneous reaction of acetic acid on α-Al(2)O(3), MgO, and CaCO(3) particles under both dry and humid conditions while the effect of reactions on the hygroscopic behavior of these particles was also measured. In all cases, formation of acetate is significantly enhanced in the presence of surface water. However, the reaction extent varied with the mineral phase of these particles. For α-Al(2)O(3), the reaction is limited to the surface with the formation of surface coordinated acetate under both dry and humid conditions. For MgO, the bulk of the particle is involved in the reaction and Mg(CH(3)COO)(2) is formed under both dry and humid conditions, although it exhibits a saturation effect under dry conditions. In the case of CaCO(3), acetic acid uptake is limited to the surface under dry conditions while it leads to the decomposition of the bulk of CaCO(3) under humid conditions. While coordinated surface acetate species increased the water adsorption capacity slightly, the formation of bulk acetate promoted the water absorption capacity greatly. This study demonstrated that heterogeneous reaction between CH(3)COOH and mineral dust is not only an important sink for CH(3)COOH, but also has a significant effect on the hygroscopic behavior of mineral dust.
Field measurements showed that there exists a correlation between nitrate and sulfate on mineral dust. In this work, the synergistic mechanism of adsorption and reaction between SO2 and NO2 on gamma-alumina was studied using in situ diffusion reflectance infrared Fourier spectroscopy (in situ DRIFTS) and temperature programmed desorption (TPD). The results revealed that the reaction pathway of NO2 adsorbed on alumina was altered in the presence of SO2. In the absence of SO2, nitrite was found to be an intermediate in the oxidation of NO2 to surface nitrate species. However, in the presence of SO2, the formation of nitrite was inhibited and a new intermediate, dinitrogen tetraoxide (N2O4), was observed. On the other hand, surface tetravalent sulfur species S(IV), including bisulfite and sulfite, were oxidized to sulfate in air condition when NO2 was present. The atmospheric implication of this synergistic effect was also discussed.
An ultimate goal of spintronics is to control magnetism via electrical means. One promising way is to utilize a current-induced spin-orbit torque (SOT) originating from the strong spin-orbit coupling in heavy metals and their interfaces to switch a single perpendicularly magnetized ferromagnetic layer at room temperature. However, experimental realization of SOT switching to date requires an additional in-plane magnetic field, or other more complex measures, thus severely limiting its prospects. Here we present a novel structure consisting of two heavy metals that delivers competing spin currents of opposite spin indices. Instead of just canceling the pure spin current and the associated SOTs as one expects and corroborated by the widely accepted SOTs, such devices manifest the ability to switch the perpendicular CoFeB magnetization solely with an in-plane current without any magnetic field. Magnetic domain imaging reveals selective asymmetrical domain wall motion under a current. Our discovery not only paves the way for the application of SOT in nonvolatile technologies, but also poses questions on the underlying mechanism of the commonly believed SOT-induced switching phenomenon.
Nitrous acid (HONO) is an important source of hydroxyl radical (OH) that determines the fate of many chemically active and climate relevant trace gases. However, the sources and the formation mechanisms of HONO remain poorly understood. In this study, the effect of SO on the heterogeneous reactions of NO on MgO as a mineral dust surrogate was investigated. The reactivity of MgO to NO is weak, while coexisting SO can increase the uptake coefficients of NO on MgO by 2-3 orders of magnitude. The uptake coefficients of NO on SO-aged MgO are independent of NO concentrations in the range of 20-160 ppbv and relative humidity (0-70%RH). The reaction mechanism was demonstrated to be a redox reaction between NO and surface sulfite. In the presence of SO, NO was reduced to nitrite under dry conditions, which could be further converted to gas-phase HONO in humid conditions. These results suggest that the reductive effect of SO on the heterogeneous conversion of NO to HONO may have a significant contribution to the unknown sources of HONO observed in polluted areas (for example, in China).
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