Abstract. The Greenland Ice Sheet Project 2 glaciochemical series (sodium, potassium, ammonium, calcium, magnesium, sulfate, nitrate, and chloride) provides a unique view of the chemistry of the atmosphere and the history of atmospheric circulation over both the high latitudes and mid-low latitudes of the northern hemisphere. Interpretation of this record reveals a diverse array of environmental signatures that include the documentation of anthropogenically derived pollutants, volcanic and biomass burning events, storminess over marine surfaces, continental aridity and biogenic source strength plus information related to the controls on both high-and low-frequency climate events of the last 110,000 years. Climate forcings investigated include changes in insolation of the order of the major orbital cycles that control the long-term behavior of atmospheric circulation patterns through changes in ice volume (sea level), events such as the Heinrich events (massi've discharges of icebergs first identified in the marine record) that are found to operate on a 6100-year cycle due largely to the lagged response of ice sheets to changes in insolation and consequent glacier dynamics, and rapid climate change events (massive reorganizations of atmospheric circulation) that are demonstrated to operate on 1450-year cycles. Changes in insolation and associated positive feedbacks related to ice sheets m•y assist in explaining favorable time periods and controls on the amplitude of massive rapid climate change events. Explanation for the exa•t timing and global synchroneity of these events is, however, more complicated. Preliminary evidence points to possible solar variability-climate associations for these events and perhaps others that are embedded in our ice-corederived atmospheric circulation records.

Despite the recent efforts to investigate the distribution and fate of persistent organic pollutants in the tropical and subtropical regions of Asia, very little was known about the temporal change of polychlorinated biphenyls (PCBs) in the environmental ecosystem of China. In this study, three dated sediment cores collected from the Pearl River Delta of southern China were analyzed for a large suite of PCB congeners, from which the temporal profiles of PCB abundances, fluxes, and homologue patterns were constructed. The sedimentary inventories of total PCBs at the sampling sites ranged from 480 to 1310 ng/cm2, at the low end of the worldwide figures. Although production and use of PCBs have been banned or highly restricted in China since the early 1980s, the fluxes of total PCBs continued to increase in the Pearl River Delta sediments. There was a concurrent increase of PCB fluxes and gross domestic product per capita in the region from 1980 to 1997, and a decline of agricultural land use was evident at the same time. Apparently, large-scale land transform since the early 1980s as well as emissions from the PCB-containing electrical equipments were responsible for the sharp rise of PCB fluxes in the recent sediments. The difference in the PCB homologue patterns from 1940 to the mid-1970s was probably indicative of the different timelines of PCB usage in Macao/Hong Kong and mainland China and the differenttypes of technical PCBs commercially used. PCBs were detectable in sediments deposited well before the time frame when production of PCBs began (before 1930) and were relatively enriched in the less chlorinated homologue groups (3Cl and 4Cl PCBs), suggesting the downward mobility of lightly chlorinated PCB congeners in the sediment column.

The coastal region off Macao is a known depositional zone for persistent organic pollutants (POPs) in the Pearl River Delta and Estuary of southern China and an important gateway for the regional contributions of contamination to the globe. This paper presents a comprehensive assessment of the input sources and transport pathways of polycyclic aromatic hydrocarbons (PAHs) found in the coastal sediments of Macao, based on measurements of 48 2-7 ring PAHs and 7 sulfur/oxygenated (S/O) PAH derivatives in 45 sediment, 13 street dust, and 68 aerosol samples. Total sediment PAHs concentrations ranged from 294 to 12741 ng/g, categorized as moderate contamination compared to other regions of Asia and the world. In addition, the PAH compounds appeared to be bound more strongly to aromatics-rich soot particles than to natural organic matter, implying a prevailing atmospheric transport route for PAHs to Macao's coast. Compositional analysis and principal component analysis (PCA) suggested that different classes of PAHs in the coastal sediments of Macao may have been derived from different input sources via various transport pathways. For example, alkylated and S/O PAHs were likely derived from fossil fuel leakage and transported to sediments by both aerosols particles and street runoff. High-molecular-weight parent PAHs were predominantly originated from automobile exhausts and distributed by direct and indirect atmospheric deposition. Low-molecular-weight parent PAHs, on the other hand, may have stemmed from lower temperature combustion and fossil fuel (such as diesel) spillage from ships and boats and were transported to sediments by river runoff or direct discharge as well as by air-water exchange.

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The First Bend on the Yangtze River (China), the point where the river ceases flowing toward the south and heads toward the northeast, has been one of the most strongly debated geomorphic features in Asia because it holds the key to understanding the history of the Yangtze River and is linked to the tectonically driven surface uplift of the southeastern Tibetan Plateau. Mid- to upper Eocene sedimentary rocks preserved in the Jianchuan Basin located immediately southwest of the First Bend demonstrate that a large river system, presumably the paleo–Jinshajiang River (the upper Yangtze), used to flow south through that region. Provenance analysis of sediments over the wider region, based mostly on U-Pb dating of detrital zircon grains, confirms that the once south-flowing paleo–Yangtze River originated in the Tibetan Plateau and flowed into the South China Sea. Inversion of the Jianchuan Basin, starting in or after the latest Eocene and associated with wider plateau surface uplift at that time, caused the river to be diverted toward the northeast where it was confined along tectonic lineaments associated with strike-slip faulting, giving birth to the First Bend, a major step in the formation of the modern Yangtze River.

Greenland ice core records provide clear evidence of rapid changes in climate in a variety of climate indicators. In this work, rapid climate change events in the Northern and Southern hemispheres are compared on the basis of an examination of changes in atmospheric circulation developed from two ice cores. High-resolution glaciochemical series, covering the period 10,000 to 16,000 years ago, from a central Greenland ice core and a new site in east Antarctica display similar variability. These findings suggest that rapid climate change events occur more frequently in Antarctica than previously demonstrated.

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The relationships between the concentration and the flux of chemical -K + NH4 + Mg 2+ Ca 2+) versus snow accumulaspecies (Cl-, NO3 , SO42-, Na +, , , , tion rate were examined at GISP2 and 20D in Greenland, Mount Logan from the St. Elias Range, Yukon Territory, Canada, and Sentik Glacier from the northwest end of the Zanskar Range in the Indian Himalayas. At all sites, only nitrate flux is significantly (a = 0.05) related to snow accumulation rate. Of all the chemical series, only nitrate concentration data are normally distributed. Therefore we suggest that nitrate concentration in snow is affected by postdepositionaJ exchange with the atmosphere over a broad range of environmental conditions. The persistent summer maxima in nitrate observed in Greenland snow over the entire range of record studied (the last 800 years) may be mainly due to NO• released from peroxyacetyl nitrate by thermal decomposition in the presence of higher OH concentrations in summer. The late winter/early spring nitrate peak observed in modern Greenland snow may be related to the buildup of anthropogenically derived N Oy in the Arctic troposphere during the long polar winter. Legrand, 1989; McElroy, 1989; Mayewski et al., 1993a, 1994]. Nitrate is one of the major chemical species in polar snow. As such, measurements of nitrate in ice cores may provide information for understanding the complex atmospheric nitrogen cycle [e.g., N½ubau½r and Heumann, 1988; Legrand and Kirchner, 1990; Mayewski and Legrand, 1990; Mayewski et al., 1990a; Mulvaney and Wolff, 1993]. However, the sources, transport pathways, and scavenging processes of nitrate deposited on glaciers are not well understood [.Wolff, 1995]. Understanding these relationships will improve our interpreta-Paper number 94JD03115. 0148-0227/95/94 JD-03115505.00 tion of nitrate data retrieved f•om worldwide ice cores. The relationships between snow accumulation rate and nitrate concentration/flux are important because they can be used to asses the dominant processes of nitrate incorporation into snow. The seasonal variation of nitrate concentration in snow is presumably related to the source of nitrate precursor in the atmosphere. Previous studies conducted by Herron [1982], Legrand and Delmas [1986], and Legrand and Kirchner [1990] investigated relationships between nitrate concentration and flux versus snow accumulation rate in Greenland and Antarctica. However, there is a discrepancy in their conclusions. Herron [1982] concluded that nitrate concentration decreased with increasing snow accumulation rate, whereas Legrand and Delmas [1986] and Legrand and Kirchner [1990] found that nitrate concentration was independent of snow accumulation rate. In this paper we reevaluate this relationship using highresolution snow chemical series from central Greenland as well as other series from southern Greenland, northwest Canada, and central Asia. Annual nitrate summer peaks in snow have been reported for both Greenland and Antarctica [Finkel et al., 1986; Mayewski et al., 1987, 1990b; Davidson et al...