A well-developed porous structure and ultrahigh surface area of porous carbons are essential for challenging the gas adsorption. Herein, we synthesized biomass-based porous carbon with a facile and effectively adjustable pore structure. The maximum surface area of activated carbon is up to 3839 m 2 g −1 , and high micropores and narrow mesopores (1.94 mL g −1 with d < 3 nm) are obtained. The tailored porous carbons are extensively applied in the energy and environment fields, such as their improved acetone adsorption, CO 2 capture, and light hydrocarbon separation. The porous carbon exhibits record-high acetone (i.e., 26.2 mmol•g −1 at 18 kPa and 25 °C) and CO 2 uptake (i.e., 29.5 mmol•g −1 at 30 bar and 25 °C) among reported carbons at relative high pressure. Besides, the UC800 exhibits superior C 2 H 6 and C 3 H 8 uptake of 7.19 and 12.02 mmol•g −1 , respectively. The C 2 H 6 /CH 4 and C 3 H 8 /CH 4 selectivity of the UC800 are up to 9.1−14.6 and 41.8−63.2, respectively. The simple method can open the door to design and develop highly porous carbons with a desired porous structure for the gas adsorption application.
We
used an innovative approach involving hot pressing, low energy
consumption, and no adhesive to transform bamboo biomass into a natural
sustainable fiber-based biocomposite for structural and furniture
applications. Analyses showed strong internal bonding through mechanical
“nail-like” nano substances, hydrogen, and ester and
ether bonds. The biocomposite encompasses a 10-fold increase in internal
bonding strength with improved water resistance, fire safety, and
environmentally friendly properties as compared to existing furniture
materials using hazardous formaldehyde-based adhesives. As compared
to natural bamboo material, this new biocomposite has improved fire
and water resistance, while there is no need for toxic adhesives (mostly
made from formaldehyde-based resin), which eases the concern of harmful
formaldehyde-based VOC emission and ensures better indoor air quality.
This surpasses existing structural and furniture materials made by
synthetic adhesives. Interestingly, our approach can 100% convert
discarded bamboo biomass into this biocomposite, which represents
a potentially cost reduction alternative with high revenue. The underlying
fragment riveting and cell collapse binding are obviously a new technology
approach that offers an economically and sustainable high-performance
biocomposite that provides solutions to structural and furniture materials
bound with synthetic adhesives.
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