Tsunami traveling in an unsmooth boundary is studied, where the boundary is considered as a fractal surface, and mass conservation and moment conservation in a fractal space are established, and a fractal derivative-based tsunami model is established. Other discontinuous boundaries can be treated in a similar way.
This review focuses on various side chain groups based on PDAs published over the last 3 years, covering urea, melamine, ferriferous oxide and coumarin. Perspectives on the remaining challenges and future developments are also proposed.
Advances in transition-metal (Ru, Co, Cu, and Fe) complex-based catalysts since 2000 are briefly summarized in terms of catalyst selection and application for photocatalytic H2 evolution.
Inspired by the "lotus effect", we proposed a facile synthetic route toward raspberry-like PS@SiO 2 microspheres, which further lead to superhydrophobic surfaces. In this approach, monodispersed polystyrene (PS) microspheres were first synthesized via dispersion polymerization using polyvinylpyrrolidone (PVP) as stabilizer. The obtained PS microspheres were then used as template microspheres for biomimetic silification using tetraethyl orthosilicate (TEOS) as precursor. Upon adjusting the molecular weight of PVP and the concentration of NH 3 $H 2 O, the surface roughness of PS@SiO 2 microspheres can be well controlled. Furthermore, after hydrophobization treatment, by dropcasting the raspberry-like PS@SiO 2 microspheres onto a glass slide, dual-scale films were obtained, which had a similar surface morphology to that of the lotus leaf, exhibiting a water contact angle of 163.3 and water contact angle hysteresis of 4 . In addition, the oil-water separation ability of hydrophobic raspberry microsphere treated steel mesh was investigated. The results demonstrated excellent oil-water separation efficiency and reusability. This facile and robust synthesis technique for constructing a superhydrophobic surface hold great potential application in versatile and large-scale oilwater separation.
Organic compounds that contain nitrogen are very important intermediates in pharmaceutical and chemical industry. Hydroamination is the reaction that can form
C
–
N
bond with high atom economy. The research progress in metals catalyzed hydroamination of alkenes and alkynes from the perspective of reaction mechanism is categorized and summarized.
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