Transfer printing that enables heterogeneous integration of materials in desired layouts offers unprecedented opportunities for developing high-performance unconventional electronic systems. However, large-area integration of ultrathin and delicate functional micro-objects with high yields in a programmable fashion still remains as a great challenge. Here, we present a simple, cost-effective, yet robust transfer printing technique via a shape-conformal stamp with actively actuated surface microstructures for programmable and scalable transfer printing with high reliability and efficiency. The shape-conformal stamp features the polymeric backing and commercially available adhesive layer with embedded expandable microspheres. Upon external thermal stimuli, the embedded microspheres expand to form surface microstructures and yield weak adhesion for reliable release. Systematic experimental and computational studies reveal the fundamental aspects of the extraordinary adhesion switchability of stamp. Demonstrations of this protocol in deterministic assemblies of diverse challenging inorganic micro-objects illustrate its extraordinary capabilities in transfer printing for developing high-performance flexible inorganic electronics.

Actuators with fast and precise controllable responses are highly in demand for implementing agilely accurate mechanical movements in smart robots, intelligent sensors, biomimetic devices, and so on. Here, we report a graphene-based moisture actuator with accurately controllable direction and position responses achieved by a fast, controlled, and even programmable one-step laser reduction method. The laser reduction-induced oriented microstructures help to precisely guide the direction and location of the moisture response in graphene-based Janus films. The excellent moisture–mechanical response behaviors in these novel moisture actuators originate from the Janus structures and the periodic microstructures of a line-scanned layer. Our customized complex intelligent devices such as drums, bands, and three-dimensional wave humidity drives can highly match and verify the finite element simulations, which will inspire the creation of further smart robot designs for accurate deformation.

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