We report the synthesis, by solvothermal methods, of the tetradecametallic cluster complexes [M14(L)6O6(OMe)18Cl6] (M=FeIII, CrIII) and [V14(L)6O6(OMe)18Cl6-xOx] (L=anion of 1,2,3-triazole or derivative). Crystal structure data are reported for the {M14} complexes [Fe14(C2H2N3)6O6(OMe)18Cl6], [Cr14(bta)6O6(OMe)18Cl6] (btaH=benzotriazole), [V14O6(Me2bta)6(OMe)18Cl6-xOx] [Me2btaH=5,6-Me2-benzotriazole; eight metal sites are VIII, the remainder are disordered between {VIII-Cl}2+ and {VIV=O}2+] and for the distorted [FeIII14O9(OH)(OMe)8(bta)7(MeOH)5(H2O)Cl8] structure that results from non-solvothermal synthetic methods, highlighting the importance of temperature regime in cluster synthesis. Magnetic studies reveal the {Fe14} complexes to have ground state electronic spins of S

The synthesis, structure, magnetic and electronic properties of soluble transition metal phosphonate cages utilizing tritylphosphonic acid (TPA) as ligand are reported.

The synthesis, crystal structure and preliminary magnetic studies are reported for a very highly reduced, VIV8VIII2, polyoxo(alkoxo)vanadate with a unique square prismatic topology.

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We realize a high-stability laser by modulation transfer spectroscopy and apply it to implement a high-performance compact optically pumped cesium beam atomic clock. Evaluated by the optical heterodyne method with two identical frequency-stabilized lasers, the frequency instability of the 852 nm laser directly referenced on thermal atoms is 2.6×10−13 at the averaging time of 5 s. Factors degrading the frequency stability of the laser are analyzed, and we will further control it to reduce the frequency noise of the laser. By comparing with a Hydrogen maser, the measured Allan deviation of the high-stability-laser-based cesium beam atomic clock is 2 × 10 − 12 / τ , dropping to 1×10−14 in less than half a day of averaging time. To our knowledge, the Allan deviation of our cesium clock is better than that of any reported compact cesium beam atomic clocks at the averaging time of half-day. The high-performance atomic clock can promote the fields in metrology and timekeeping, and the high-stability laser additionally possesses great potential to be a compact optical frequency standard.

The novel tumor suppressor RASSF1A is frequently inactivated during human tumorigenesis by promoter methylation. In this study, we detected the RASSF1A promoter methylation by methylated-specific PCR and investigated RASSF1A gene expression by semi-quantitative RT-PCR and immunohistochemical staining in 36 cases of breast cancer and their adjacent normal tissues in Chinese women. The promoter methylation of the RASSF1A gene was found to be a frequent event in the breast cancers (61.1%). RASSF1A methylation was not found in the matched adjacent normal tissues. The loss frequency of RASSF1A mRNA was 33.3% and that of the RASSF1A protein was 44.4% in breast cancers. RASSF1A mRNA and protein were all expressed in adjacent normal tissues. The mRNA and protein expression level of RASSF1A was significantly lower in breast cancer than in adjacent normal tissue. However, the promoter methylation of the RASSF1A gene in breast cancers were not correlated with clinical parameters, such as ages, histological types, TNM stages and lymph node metastases. Thus, the promoter methylation of RASSF1A was one reason for the low level of RASSF1A mRNA and protein expression and was a frequent event in primary sporadic breast tumorigenesis in Chinese women.