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A method using a low-temperature Si (LT-Si) buffer layer is developed to grow a SiGe epilayer with low density of dislocations on a Si substrate by molecular-beam epitaxy. In this method, a LT-Si layer is used to release the stress of the SiGe layer. The samples have been investigated by x-ray double-crystal diffraction and transmission electron microscopy. The results indicate that the LT-Si is effective to release the stress and suppress threading dislocations.

An actively reconfigurable broadband terahertz (THz) metamaterial functional device based on the phase-change material vanadium dioxide (VO2) and two-dimensional graphene material is theoretically proposed and demonstrated. The device has excellent tolerance under oblique incidence. When the VO2 is in the metallic state, and the Fermi energy of graphene is fixed at 0.1 eV, the designed device acts as a broadband THz absorber in the transverse magnetic (TM) polarization mode. The absorptance bandwidth exceeds 0.55 THz with a complete absorption intensity of more than 90%. In this state, the absorber operates as a broadband modulator with the total modulation depth exceeding 91.5% as the continually decreased conductivity of VO2 from 200000 S/m to 10 S/m. In the transverse electric (TE) polarization process, the structure behaves as a dual-band absorber with two perfect absorption peaks. When the conductivity of VO2 is changed, the tunable absorber can also be regarded as an absorptance modulator, with a maximum modulation intensity of 92.1%. Alternatively, when VO2 behaves as an insulator at room temperature in the TE polarization mode, a strong broadband electromagnetically induced transparency (EIT) window is obtained, with a bandwidth exceeding 0.42 THz in the transmittance spectrum. By varying the Fermi energy of graphene from 0 to 0.9 eV, the EIT-like window or broadband transmission spectrum (in TM mode) can be switched. The results indicate that the device can also be operated as a modulator in the transmission mode. The impedance matching theory is used, and electric field distributions are analyzed to quantify the physical mechanism. An advantage of the manipulation of the polarization angle is that the modulation performance of the proposed multi-functional THz device can be regulated after fabricated.

High and efficient deliverability of stimulated reservoir volume through a hydraulic fracturing treatment relies on three segments: fluid flow from matrix to the interface between fracture and matrix media, fluid-rock interaction at the fracture-matrix interface, and conductivity of fracture network. Thus, fluids and salt exchange between matrix and fracture network are critical and worth detailed investigation. Moreover, matrix imbibition as an important EOR mechanism has been extensively studied but the focus was mostly given to capillary effect. However, for shale, due to the pore structure and clay content, some physico- or electro-chemical forces at molecular level cannot be overlooked anymore, such as osmosis. A multi-mechanistic numerical shale matrix imbibition model is developed. The model takes into account dynamic water movement caused by capillary pressure and osmotic pressure as a function of water saturation and salt concentration, respectively. The rock matrix is considered as the mixture of two different components, one with small nano/micro-pores and semi-permeable membrane property and the other having larger meso-pores. The model properly simulates water and salt transportation occurring across the matrix-fracture network contact surface driven by capillarity, osmosis, and salt diffusion. To honor the physics, the salt/ions concentration equation differs from previous work by removing the osmosis component and a new membrane efficiency coefficient is defined and properly incorporated in the model. Spontaneous imbibition test results were used for matching and validation purposes. The simulation results well explained laboratory high-salinity water imbibition curve, which can be divided into three processes. Initially, a capillary driven imbibition sucks high salt-concentration water into matrix near the matrix-fracture contact surface. However, due to the significant salinity contrast between imbibed fluids and in-situ matrix salinity, a drainage process can be induced. Eventually, as salinity difference decreases and osmosis is weakening, final imbibition stage starts. This model provides a basis for laboratory measurements interpretation and brings some insights to reveal the underlying mechanisms for field post-frac flow-back behavior.

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