This study reports the concentration levels and distribution pattern of the persistent organochlorine pesticide (OCPs) residues in the water and bed-sediments of the Gomti River collected seasonally over a period of 2 years. The water and bed-sediment samples were collected from eight different sites and analyzed for aldrin, dieldrin, endrin, HCB, HCH isomers, DDT isomers/metabolites, endosulfan isomers (alpha and beta), endosulfan sulfate, heptachlor and its metabolites, alpha-chlordane, gamma-chlordane and methoxychlor. In the river water and sediments SigmaOCPs residues ranged between 2.16 and 567.49 ng l(-1) and 0.92 and 813.59 ng g(-1), respectively. The results, further, suggested that source of DDT contamination is from the aged and weathered agricultural soils with signature of recently used DDT in the river catchments. To assess any adverse effect of OCPs contamination on river's biological component, the threshold effect level (TEL) was used. The results revealed that bed-sediments of the Gomti River are contaminated with lindane, endrin, heptachlor epoxides and DDT, particularly at site-4 and may contribute to sediment toxicity in the freshwater ecosystem of the river.
This study reports the levels and distribution patterns of selected polycyclic aromatic hydrocarbons (PAHs) in fish samples of the Gomti river, India, collected from three sites during the pre- and post-monsoon seasons of the years 2004-2005. In the fish muscles, SigmaPAHs ranged between 12.85 and 34.89 ng g(-1) wet wt (mean value: 23.98+/-6.70 ng g(-1)). Naphthalene was the most prevalent compound both in terms of detection as well as levels, while, benzo[k]fluoranthene, benzo(a)pyrene, and indeno(123-cd)pyrene + benzo(ghi)perylene could not be detected in any of the sample. Low-molecular weight PAHs were observed dominating over the high molecular weight PAHs.
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