The planar molecule of the title compound, C9H10ClNOS, displays an E conformation about the central C—N bond and exists in the thione form. In the crystal structure, centrosymmetrically related molecules associate into dimers via N—H⋯S hydrogen‐bonding interactions.
The title compound, [Au(C
10
H
12
NOS)(C
18
H
15
P)], features a linear
S
,
P
-donor set about the central Au atom. The thiocarbamate ligand is orientated to place the aryl ring in close proximity to Au [the closest Au⋯C distance is 3.238 (4) Å], which results in a small deviation from the ideal linear P—Au—S geometry.
The AuI atom in the title compound, [Au(C9H9ClNOS)(C18H15P)]·0.5CH2Cl2, exists within a slightly distorted linear geometry defined by an S,P donor set [S—Au—P angle = 178.01 (4)°]; a close intramolecular Au⋯O contact [2.964 (4) Å] also occurs. In the crystal structure, molecules are linked into supramolecular chains propagating along [010] by C—H⋯N, C—H⋯S and C—H⋯π interactions. The solvent molecule is disordered about a twofold rotation axis.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.