The goal of this research is to quantify the fibrillar adhesive energy in ultra-high molecular weight polyethylene fibers, characteristic of nanoscale fibril interactions. Quantification of these energies is vital to the understanding of fibrillar deformation mechanisms that have been shown to play an important role in fiber performance. This is achieved through the development and implementation of a nanosplitting technique developed through the use of AFM-enabled nanoindentation. This technique allows the quantification of nanoscale adhesive energies through careful monitoring of load and unload curves as well as examination of the residual split through high-resolution AFM images. Results indicate that the average nanoscale fibril adhesive energy is over 3 times larger than the energy expected from van der Waals interactions alone. This indicates that a significant degree of physical interactions exist between fibrils, beyond van der Waals interactions, in the form of tie-molecules, fibrillar network junctions, and bridging lamellar crystals.
In this work, a variable angle, single fiber peel test is developed to analyze the effects of fiber structure on the mixed mode failure within ultra high molecular weight polyethylene fibers. The Mode I and Mode II peel energy release rates are quantified and the effects of fiber meso/nanostructure on these modes are examined. Comparison of the load-extension curves from the peel test with in-situ video, and post-mortem analysis using high-resolution microscopy techniques indicates that Mode I and Mode II splitting are both significantly influenced by the deformation of nanoscale fibrils within a mesoscale network. The fibrils in the network are placed in tension across the peel/shear interface resulting in elevated values of peel energy release rates with an increasing number of engaged fibrils. The number of engaged fibrils is shown to increase with decreasing peel angle and increasing Mode II failure contribution. A bi-linear mixed-mode failure criterion is established. The results, and analysis of the fiber structure are discussed in context of their implications for load pathways in the fiber.
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