A kinetic study of the silver(1)-catalyzed oxidation of tris(1,lO-phenanthroline)iron(II) with peroxodiphosphate was carried out by estimating tris-complex at 510 nm. The reaction is found to conform to the rate law (i).with K2 and K3 being the acid dissociation constants of H~P208-and H~Pz082-, respectively. The silver(1) catalysis in the reaction has been explained on the basis of complex formation between pdp and silver(1).
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