2D materials and the associated heterostructures define an ideal material platform for investigating physical and chemical properties, and exhibiting new functional applications in (opto)electronic devices, electrocatalysis, and energy storage. 2D transition metal dichalcogenides (2D TMDs), as a member of the 2D materials family including 2D semiconducting TMDs (s-TMDs) and 2D metallic/semimetallic TMDs (m-TMDs) have attracted considerable attention in the scientific community. Over the past decade, the 2D s-TMDs have been extensively researched and reviewed elsewhere. Because of their distinctive physical properties including intrinsic magnetism, chargedensity-wave order and superconductivity, and potential applications, such as high-performance electronic devices, catalysis, and as metal electrode contacts, 2D m-TMDs have grabbed widespread attention in recent years. However, reviews demonstrating the m-TMDs systematically and comprehensively have been rarely reported. Here, the recent advances in 2D m-TMDs in the aspects of their unique structures, synthetic approaches, distinctive physical properties, and functional applications are highlighted. Finally, the current challenges and perspectives are discussed.

Abstract

Cashew is an emerging crop in the seasonally 'wet-dry' tropical regions of northern Australia. In North Queensland flowering and fruiting of cashew coincides with the dry season (May-November). During this period growers sprinkler irrigate at 500 L/tree.week. A 3-year (1996-98) experiment compared this strategy with alternatives, including no irrigation or drip irrigation in which 115 or 230 L/tree.week was applied by drippers placed near the tree trunk and near the canopy drip line throughout the dry season. Measurements of soil water to 1.3 m, leaf gas exchange, chlorophyll fluorescence, tree sap flow and yield were made. Data collected in the first 2 years showed that the water requirement of the trees increased progressively as the crop load and evaporative demand increased during the dry season. During the final year of the study, additional sprinkler and drip treatments, in which water applications were progressively increased during the dry season, were introduced.The productivity of cashew in this experiment was strongly influenced by irrigation treatments, ranging (over all years) from 42 to 160 g nut/m 2 canopy surface area. Depletion of plant-available water in the root zone was associated with a reduction in photosynthesis mediated by partial stomatal closure. These effects of soil drying were evident in all irrigated treatments during the mid and late stages of the dry season but were more severe in treatments receiving the least water. When irrigation was withheld until the mid-stage of the dry season the trees had similar yields to those that were irrigated throughout, emphasising the importance of providing adequate irrigation between nut set and harvest.When rainfall from January to September in each year of the study was taken into account, there was a strong linear relationship between nut yield and water applied (rainfall + irrigation), with each extra kilolitre of water applied resulting in about 6 extra g nut/m 2 canopy surface area. This linear relationship was based on water application in the range 25-50 kL per season. It is possible that if the seasonal water application had exceeded 50 kL the marginal response to extra water may have diminished. Using drippers was slightly more efficient than sprinklers, with drip-irrigated trees requiring about 5% less water applied to achieve a given nut yield.In years when rainfall is average, and subject to other economic factors, growers in North Queensland should aim to irrigate about 500 L/tree.week. In years of low rainfall between January and September it is likely that yield will be improved by applying more irrigation water; high rainfall during these months of the year may reduce the irrigation requirement. In all cases growers should be careful to accurately monitor water applications, particularly when the total (from rainfall + irrigation) exceeds 40 kL/tree for the season.

No abstract

Underground space has to be monitored for regional coverage deformations. This issue remains a challenge for current deformation monitoring techniques. In this study, a new high-coverage regional monitoring method is presented to address underground space deformation by using the divergent feature of an ultrasonic sensor. The working principle for coverage regional monitoring, which uses the divergence feature of an ultrasonic beam to increase the monitoring area coverage, is proposed. Space and mathematical models for the ultrasonic beam are also established. An ultrasonic spherical sensor device is designed to achieve all-round monitoring of underground deformation. A longitude–latitude color map histogram is proposed, which enables automatic detection and tracking of omni-directional structural deformation. The new method is illustrated via experiments to determine its validity for deformation monitoring.