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Subduction zones are one of the most important sites of chemical interchange between the Earth's surface and interior. One means of explaining the high Fe 3+ /ƩFe ratios and oxidized nature of primary arc magmas is the transfer of sulfate (SO X), carbonate (CO 3-), and/or iron (Fe 3+) bearing fluids from the slab to the overlying mantle. Iron mobility and Fe stable isotope fractionation in fluids are influenced by Fe redox state and the presence of chlorine and/or sulfur anions. Here we use Fe stable isotopes (d 56 Fe) as a tracer of iron mobility in serpentinites from Western Alps metaophiolites, which represent remnants of oceanic lithosphere that have undergone subduction-related metamorphism and devolatilization. A negative correlation (R 2 = 0.72) is observed between serpentinite bulk d 56 Fe and Fe 3+ /ƩFe that provides the first direct evidence for the release of Fe-bearing fluids during serpentinite devolatilization in subduction zones. The progressive loss of isotopically light Fe from the slab with increasing degree of prograde metamorphism is consistent with the release of sulfate-rich and/or hypersaline fluids, which preferentially complex isotopically light Fe in the form of Fe(II)-SO X or Fe(II)-Cl 2 species. Fe isotopes can therefore be used as a tracer of the nature of slab-derived fluids.

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The formation of mountain belts or rift zones is commonly attributed to interactions between plates along their boundaries, but the widely distributed deformation of Asia from Himalaya to the Japan Sea and other back‐arc basins is difficult to reconcile with this notion. Through comparison of the tectonic and kinematic records of the last 50 Ma with seismic tomography and anisotropy models, we show that the closure of the former Tethys Ocean and the extensional deformation of East Asia can be best explained if the asthenospheric mantle transporting India northward, forming the Himalaya and the Tibetan Plateau, reaches East Asia where it overrides the westward flowing Pacific mantle and contributes to subduction dynamics, distributing extensional deformation over a 3,000‐km wide region. This deep asthenospheric flow partly controls the compressional stresses transmitted through the continent‐continent collision, driving crustal thickening below the Himalayas and Tibet and the propagation of strike‐slip faults across Asian lithosphere further north and east, as well as with the lithospheric and crustal flow powered by slab retreat east of the collision zone below East and SE Asia. The main shortening direction in the deforming continent between the collision zone and the Pacific subduction zones may in this case be a proxy for the direction of flow in the asthenosphere underneath, which may become a useful tool for studying mantle flow in the distant past. Our model of the India‐Asia collision emphasizes the role of asthenospheric flow underneath continents and may offer alternative ways of understanding tectonic processes.

International audienceThe combination of U–Pb, Lu–Hf and O isotopic analyses in global zircon databases has recently been used to constrain continental crustal growth and evolution. To identify crust-forming events, these studies rely on the assumption that new crust is formed from depleted mantle sources. In contrast, this work suggests that post-collisional mafic magmas and their derivatives represent a non-negligible contribution to crustal growth, despite having zircons with “crust-like” Hf–O isotopic characteristics. We address this paradox and its implications for crustal evolution on the basis of a case study from the Variscan French Massif Central (FMC). The late stages of continental collisions are systematically marked by the emplacement of peculiar mafic magmas, rich in both compatible (Fe, Mg, Ni, Cr) and incompatible elements (K2O, HFSE, LREE) and displaying crust-like trace element patterns. This dual signature is best explained by melting of phlogopite- (and/or amphibole-) bearing peridotite, formed by contamination of the mantle by limited amounts (10–20%) of crustal material during continental subduction shortly preceding collision. Mass balance constraints show that in melts derived from such a hybrid source, 62–85% of the bulk mass is provided by the mantle component, whereas incompatible trace elements are dominantly crustal in origin. Thereby, post-collisional mafic magmas represent significant additions to the crust, whilst their zircons have “crustal” isotope signatures (e.g. −2<εHft<−9−2<εHft<−9 and View the MathML source+6.4<δO18<+10‰ in the FMC). Because post-collisional mafic magmas are (i) ubiquitous since the late Archean; (ii) the parental magmas of voluminous granitoid suites; and (iii) selectively preserved in the geological record, zircons crystallized from such magmas (and any material derived from their differentiation or reworking) bias the crustal growth record of global zircon Hf–O isotopic datasets towards ancient crust formation and, specifically, may lead to an under-estimation of crustal growth rates since the late Archean