No abstract

No abstract

No abstract

No abstract

Since its market entry in 2001, ThermoWood® has become the most established form of thermal modification globally. Whilst its properties have been widely reported, there is still a need for a readily-applied quality control method to ensure treatments meet the criteria outlined by the International ThermoWood Association. One such method for quality control has focussed on the use of colour measurements. In the largest study of its kind, colour measurement data have been evaluated for Norway spruce and Scots pine subjected to the Thermo-D ThermoWood® process at twelve industrial plants between 2007 and 2018. This showed that the colour measurement according to the CIELAB* colour space on newly planed surfaces of thermally modified timber (TMT) may be used for quality control of the ThermoWood® Thermo-D process with regard to process intensity, i.e. the combined effect of temperature (212 ± 3°C) and time. In order to obtain more robust control, only the L* parameter (lightness) should be used as a quality indicator, as both a* and b* parameters for the TMT showed little variation from those of the unmodified wood and too high a scatter in values.

Thermal modification causes the darkening of wood throughout its crosssection because of chemical changes in the wood. After treatment, naturally light wood species look darker or even tropical, depending predominantly on the treatment temperature and processing time. This study investigates the suitability of using color measurement to determine treatment intensity at the industrial scale. The color was determined using the L*, a*, and b* color space, also referred to as CIELab, and the relationship between lightness (L*) and the color parameters (a*) and (b*) was investigated for thermal modification treatments at 190 and 212 °C. The wood species studied were pine (Pinus sylvestris L.) and spruce (Picea abies L.). The results showed that yellowness (+b*) and redness (+a*) had a significant prediction ability for class treatments at 190 and 212 °C, respectively. After treatment, there were no noticeable differences in color between the species, but sapwood was darker than heartwood in both untreated and thermally modified wood. The thickness of the boards had a proportionally darkening effect on the color values.

The thermal modification of wood has become the most-commonly commercialised wood modification process globally, with the ThermoWood® process currently being the most dominant. As with all commercial processes, there is a need to have a robust quality control system, with several small–scale studies undertaken to date investigating quality control using a range of analytical methods, culminating in a multi-year assessment of colour as a means of quality control. This study, as an extension to this multi-year assessment, further explores the colour of Norway spruce and Scots pine commercially modified by the ThermoWood® S and D processes, respectively, along with the mechanical properties and structural characterisation by Fourier transform infrared (FT–IR) spectroscopy and principal component analysis (PCA) to ascertain further correlations between colour and other measurable properties. Infrared spectroscopy indicated modifications in the amorphous carbohydrates and lignin, whereas the use of PCA allowed for the differentiation between untreated and modified wood. Colour measurements indicated reduced brightness, and shifting toward red and yellow colours after thermal modification, hardness values decreased, whereas MOE and MOR values were similar for modified wood compared to unmodified ones. However, by combining the colour measurements and PC scores, it was possible to differentiate between the two modification processes (Thermo–S and Thermo–D). By combining the mechanical properties and PC scores, it was possible to differentiate the untreated wood from the modified ones, whereas by combining the mechanical properties and colour parameters, it was possible to differentiate between the three groups of studied samples. This demonstrates there is a degree of correlation between the test methods, adding further confidence to the postulation of using colour to ensure quality control of ThermoWood®.

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.