Abstract.A well-documented, publicly available, global data set of surface ocean carbon dioxide (CO 2 ) parameters has been called for by international groups for nearly two decades. The Surface Ocean CO 2 Atlas (SOCAT) project was initiated by the international marine carbon science community in 2007 with the aim of providing a comprehensive, publicly available, regularly updated, global data set of marine surface CO 2 , which had been subject to quality control (QC). Many additional CO 2 data, not yet made public via the Carbon Dioxide Information Analysis Center (CDIAC), were retrieved from data originators, public websites and other data centres. All data were put in a uniform format following a strict protocol. Quality control was carried out according to clearly defined criteria. Regional specialists performed the quality control, using state-of-the-art web-based tools, specially developed for accomplishing this global team effort. SOCAT version 1.5 was made public in September 2011 and holds 6.3 million quality controlled surface CO 2 data points from the global oceans and coastal seas, spanning four decades . Three types of data products are available: individual cruise files, a merged complete data set and gridded products. With the rapid expansion of marine CO 2 data collection and the importance of quantifying net global oceanic CO 2 uptake and its changes, sustained data synthesis and data access are priorities. Data coverage MotivationThe net absorption of CO 2 by the oceans, caused by rising atmospheric CO 2 concentrations since the industrial revolution, has been responsible for removing CO 2 equivalent to approximately 50 % of the fossil fuel and cement manufacturing emissions or about 30 % of the total anthropogenic emissions, including land use change (Sabine et al., 2004). Because of the availability of the carbonate ion, an important species of the dissolved inorganic carbon pool, and carbonate sediments, the oceans have a tremendous CO 2 uptake capacity and will, on timescales of ten to hundred thousand years, absorb all but a small fraction of the fossil CO 2 that has been and will be emitted (Archer et al., 1997). Meanwhile the changes in ocean CO 2 uptake, relying on factors such as ocean circulation and biology, will be among the decisive factors for the evolution of future atmospheric CO 2 concentrations and climate development (e.g., Friedlingstein et al., 2006;Riebesell et al., 2009). Presently there are two types of globally coordinated efforts that seek to resolve the dynamics of ocean CO 2 uptake through observations: repeat hydrography and surface ocean CO 2 observations (Gruber et al., 2010;Sabine et al., 2010). While repeat hydrography aims to assess variations in the ocean inventory of CO 2 on decadal timescales, surface ocean observations may resolve variations on seasonal to interannual timescales due to the higher sampling frequency. This high sampling frequency has been made possible by the advent of autonomous instruments and sensors for the nearcontinuous determination o...

The horizontal and vertical circulation of the Weddell Gyre is diagnosed using a box inverse model constructed with recent hydrographic sections and including mobile sea ice and eddy transports. The gyre is found to convey 42 6 8 Sv (1 Sv 5 106 m3 s-1) across the central Weddell Sea and to intensify to 54 6 15 Sv further offshore. This circulation injects 36 6 13 TW of heat from the Antarctic Circumpolar Current to the gyre, and exports 51 6 23 mSv of freshwater, including 13 6 1 mSv as sea ice to the midlatitude Southern Ocean. The gyre's overturning circulation has an asymmetric double-cell structure, in which 13 6 4 Sv of Circumpolar Deep Water (CDW) and relatively light Antarctic Bottom Water (AABW) are transformed into upper-ocean water masses by midgyre upwelling (at a rate of 2 6 2 Sv) and into denser AABW by downwelling focussed at the western boundary (8 6 2 Sv). The gyre circulation exhibits a substantial throughflow component, by which CDW and AABW enter the gyre from the Indian sector, undergo ventilation and densification within the gyre, and are exported to the South Atlantic across the gyre's northern rim. The relatively modest net production of AABW in the Weddell Gyre (6 6 2 Sv) suggests that the gyre's prominence in the closure of the lower limb of global oceanic overturning stems largely from the recycling and equatorward export of Indian-sourced AABW.

The Weddell Gyre (WG) is one of the main oceanographic features of the Southern Ocean south of the Antarctic Circumpolar Current which plays an influential role in global ocean circulation as well as gas exchange with the atmosphere. We review the state‐of‐the art knowledge concerning the WG from an interdisciplinary perspective, uncovering critical aspects needed to understand this system's role in shaping the future evolution of oceanic heat and carbon uptake over the next decades. The main limitations in our knowledge are related to the conditions in this extreme and remote environment, where the polar night, very low air temperatures, and presence of sea ice year‐round hamper field and remotely sensed measurements. We highlight the importance of winter and under‐ice conditions in the southern WG, the role that new technology will play to overcome present‐day sampling limitations, the importance of the WG connectivity to the low‐latitude oceans and atmosphere, and the expected intensification of the WG circulation as the westerly winds intensify. Greater international cooperation is needed to define key sampling locations that can be visited by any research vessel in the region. Existing transects sampled since the 1980s along the Prime Meridian and along an East‐West section at ~62°S should be maintained with regularity to provide answers to the relevant questions. This approach will provide long‐term data to determine trends and will improve representation of processes for regional, Antarctic‐wide, and global modeling efforts—thereby enhancing predictions of the WG in global ocean circulation and climate.

Abstract. The Global Ocean Data Analysis Project (GLODAP) is a synthesis effort providing regular compilations of surface-to-bottom ocean biogeochemical data, with an emphasis on seawater inorganic carbon chemistry and related variables determined through chemical analysis of seawater samples. GLODAPv2.2020 is an update of the previous version, GLODAPv2.2019. The major changes are data from 106 new cruises added, extension of time coverage to 2019, and the inclusion of available (also for historical cruises) discrete fugacity of CO2 (fCO2) values in the merged product files. GLODAPv2.2020 now includes measurements from more than 1.2 million water samples from the global oceans collected on 946 cruises. The data for the 12 GLODAP core variables (salinity, oxygen, nitrate, silicate, phosphate, dissolved inorganic carbon, total alkalinity, pH, CFC-11, CFC-12, CFC-113, and CCl4) have undergone extensive quality control with a focus on systematic evaluation of bias. The data are available in two formats: (i) as submitted by the data originator but updated to WOCE exchange format and (ii) as a merged data product with adjustments applied to minimize bias. These adjustments were derived by comparing the data from the 106 new cruises with the data from the 840 quality-controlled cruises of the GLODAPv2.2019 data product using crossover analysis. Comparisons to empirical algorithm estimates provided additional context for adjustment decisions; this is new to this version. The adjustments are intended to remove potential biases from errors related to measurement, calibration, and data-handling practices without removing known or likely time trends or variations in the variables evaluated. The compiled and adjusted data product is believed to be consistent to better than 0.005 in salinity, 1 % in oxygen, 2 % in nitrate, 2 % in silicate, 2 % in phosphate, 4 µmol kg−1 in dissolved inorganic carbon, 4 µmol kg−1 in total alkalinity, 0.01–0.02 in pH (depending on region), and 5 % in the halogenated transient tracers. The other variables included in the compilation, such as isotopic tracers and discrete fCO2, were not subjected to bias comparison or adjustments. The original data and their documentation and DOI codes are available at the Ocean Carbon Data System of NOAA NCEI (https://www.nodc.noaa.gov/ocads/oceans/GLODAPv2_2020/, last access: 20 June 2020). This site also provides access to the merged data product, which is provided as a single global file and as four regional ones – the Arctic, Atlantic, Indian, and Pacific oceans – under https://doi.org/10.25921/2c8h-sa89 (Olsen et al., 2020). These bias-adjusted product files also include significant ancillary and approximated data. These were obtained by interpolation of, or calculation from, measured data. This living data update documents the GLODAPv2.2020 methods and provides a broad overview of the secondary quality control procedures and results.

Abstract. As a response to public demand for a welldocumented, quality controlled, publically available, global surface ocean carbon dioxide (CO 2 ) data set, the international marine carbon science community developed the Surface Ocean CO 2 Atlas (SOCAT). The first SOCAT product is a collection of 6.3 million quality controlled surface CO 2 data from the global oceans and coastal seas, spanning four decades . The SOCAT gridded data presented here is the second data product to come from the SOCAT project. Recognizing that some groups may have trouble working with millions of measurements, the SOCAT gridded product was generated to provide a robust, regularly spaced CO 2 fugacity ( f CO 2 ) product with minimal spatial and temporal interpolation, which should be easier to work with for many applications. Gridded SOCAT is rich with information that has not been fully explored yet (e.g., regional differences in the seasonal cycles), but also contains biases and limitations that the user needs to recognize and address (e.g., local influences on values in some coastal regions). Data coverage and parameter measuredRepository-Reference:

The distribution of noble gases and helium isotopes in the dense shelf waters of Antarctica reflects the boundary conditions near the ocean surface: air‐sea exchange, sea ice formation, and subsurface ice melt. We use a nonlinear least squares solution to determine the value of the recharge temperature and salinity, as well as the excess air injection and glacial meltwater content throughout the water column and in the precursor to Antarctic Bottom Water. The noble gas‐derived recharge temperature and salinity in the Weddell Gyre are −1.95°C and 34.95 psu near 5500 m; these cold, salty recharge values are a result of surface cooling as well as brine rejection during sea ice formation in Antarctic polynyas. In comparison, the global value for deep water recharge temperature is −0.44°C at 5500 m, which is 1.5°C warmer than the southern hemisphere deep water recharge temperature, reflecting a distinct contribution from the north Atlantic. The contrast between northern and southern hemisphere recharge properties highlights the impact of sea ice formation on setting the gas properties in southern sourced deep water. Below 1000 m, glacial meltwater averages 3.5‰ by volume and represents greater than 50% of the excess neon and argon found in the water column. These results indicate glacial melt has a nonnegligible impact on the atmospheric gas content of Antarctic Bottom Water.

The carbon cycle in seasonally sea-ice covered waters remains poorly understood due to both a lack of observational data and the complexity of the system. Here we present three consecutive seasonal cycles of upper ocean dissolved inorganic carbon (DIC) and total alkalinity measurements from Ryder Bay on the West Antarctic Peninsula. We attribute the observed changes in DIC to four processes: mixing of water masses, air-sea CO2 flux, calcium carbonate precipitation/dissolution and photosynthesis/respiration. This approach enables us to resolve the main drivers of the seasonal DIC cycle and also investigate the mechanisms behind interannual variability in the carbonate system. We observe a strong, asymmetric seasonal cycle in the carbonate system, driven by physical processes and primary production. In summer, melting glacial ice and sea ice and a reduction in mixing with deeper water reduce the concentration of DIC in surface waters. The dominant process affecting the carbonate system is net photosynthesis which reduces DIC and the fugacity of CO2, making the ocean a net sink of atmospheric CO2. In winter, mixing with deeper, carbon-rich water and net heterotrophy increase surface DIC concentrations, resulting in pH as low as 7.95 and aragonite saturation states close to 1. We observe no clear seasonal cycle of calcium carbonate precipitation/dissolution but some short-lived features of the carbonate time series strongly suggest that significant precipitation of calcium carbonate does occur in the Bay. The variability observed in this study demonstrates that changes in mixing and sea ice cover significantly affect carbon cycling in this dynamic environment. Maintaining this unique time series will allow the carbonate system in seasonally sea-ice covered waters to be better understood

The accumulation of carbon within the Weddell Gyre and its exchanges across the gyre boundaries are investigated with three recent full-depth oceanographic sections enclosing this climatically important region. The combination of carbon measurements with ocean circulation transport estimates from a box inverse analysis reveals that deepwater transports associated with Warm Deep Water (WDW) and Weddell Sea Deep Water dominate the gyre's carbon budget, while a dual-cell vertical overturning circulation leads to both upwelling and the delivery of large quantities of carbon to the deep ocean. Historical sea surface pCO 2 observations, interpolated using a neural network technique, confirm the net summertime sink of 0.044 to 0.058 ± 0.010 Pg C yr À1 derived from the inversion. However, a wintertime outgassing signal similar in size results in a statistically insignificant annual air-to-sea CO 2 flux of 0.002 ± 0.007 Pg C yr À1 (mean 1998-2011) to 0.012 ± 0.024 Pg C yr À1 (mean 2008-2010) to be diagnosed for the Weddell Gyre. A surface layer carbon balance, independently derived from in situ biogeochemical measurements, reveals that freshwater inputs and biological drawdown decrease surface ocean inorganic carbon levels more than they are increased by WDW entrainment, resulting in an estimated annual carbon sink of 0.033 ± 0.021 Pg C yr À1. Although relatively less efficient for carbon uptake than the global oceans, the summertime Weddell Gyre suppresses the winter outgassing signal, while its biological pump and deepwater formation act as key conduits for transporting natural and anthropogenic carbon to the deep ocean where they can reside for long time scales.