Several aspects concerning the origin and nature of grand solar minima remain unclear, and more high‐resolution 10Be and 14C records are needed to improve our understanding of these phenomena. Here, we report 137 new high‐precision, annually resolved radiocarbon concentrations based on oak from the Danish dendrochronology. The new record covers a period (CE 1432–1578) that encompasses most of the penultimate grand solar minima known as the Spörer Minimum. A detailed comparison between the Spörer and Maunder (CE 1640–1720) minima shows that the Spörer Minimum is associated with enhanced Δ14C variability in a band centered around the 11‐year Schwabe cycle from CE 1450 to 1479 and between CE 1545 and 1578, whereas little 11‐year variability is observed from CE 1479 to 1539. In contrast, we only observe enhanced 11‐year variability after the end of the Maunder Minimum at CE 1722–1744, which could indicate that the nature and origin of the two minima were different.

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We here present a comparison of methods for the pretreatment of a batch of tree rings for high-precision measurement of radiocarbon at the Aarhus AMS Centre (AARAMS), Aarhus University, Denmark. The aim was to develop an efficient and high-throughput method able to pretreat ca. 50 samples at a time. We tested two methods for extracting α-cellulose from wood to find the most optimal for our use. One method used acetic acid, the other used HCl acid for the delignification. The testing was conducted on background 14C samples, in order to assess the effect of the different pretreatment methods on low-activity samples. Furthermore, the extracted wood and cellulose fractions were analyzed using Fourier transform infrared (FTIR) spectroscopy, which showed a successful extraction of α-cellulose from the samples. Cellulose samples were pretreated at AARAMS, and the graphitization and radiocarbon analysis of these samples were done at both AARAMS and the radiocarbon dating laboratory at Lund University to compare the graphitization and AMS machine performance. No significant offset was found between the two sets of measurements. Based on these tests, the pretreatment of tree rings for high-precision radiocarbon analysis at AARAMS will henceforth use HCI for the delignification.

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