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Safety investment is an essential guarantee to identify and manage potential security problems in petrochemical port enterprises. The reasonability of safety investment structure determines overall security risks in an enterprise. Based on the definition of risks, combining Cobb-Douglas production function with FTA probability model, and taking Gompertz curve model as the constraint condition, structure optimization model of safety investment is built in order to minimize risks and work out the safety investment structure of petrochemical port enterprises. According to the case study, the calculations indicate that safety investment in corporate management presents a larger growth rate than past years and that unsafe act of human being is the main factor accounting for the greatest probability of occurrence, which is consistent with previous accident investigation results as well as enterprise reality. This testifies that the model is effective and that the results can guide the allocation of safety investment of petrochemical port enterprises scientifically.

To solve the problems of the rapid advance of the working face was delayed by complicated working procedure and high labor intensity, and the severe damage of roof bolt (anchor cable) induced by advanced hydraulic support, the deformation characteristics of surrounding rock, and the supporting principle of grouting truss anchor cable were analyzed theoretically by taking the roadway of 3_(down) coal seams 2326# working face in Sanhekou coal mine as the research object; then, the mechanical model of supporting structure of roadway under goaf was established. Based on this model, the optimal supporting scheme was determined, and the active advanced support technology scheme of “advanced grouting truss anchor cable” was proposed to take the place of the existing single pillar. The deformation and failure characteristics of surrounding rock of the working face leading roadway were observed and analyzed on-site. Within the allowable range of reading error, the results showed that the maximum displacement of medium-deep base point and shallow base point of two roadways was 15.2 cm and 10.9 cm, respectively; the pressure value had a more obvious jump increase when the distance between each measuring point and the working face was about 35 m, which means the range is strongly affected by the advance mining, and the area affected by advanced mining was 35 m ahead of the working face. It was observed that the lowest position of roof separation development ranged from 0.71 m to 2.73 m. The separation layer was generally distributed in the range of 0.73 m-2.49 m, and the fracture area was roughly distributed in the range of 0.01 m-0.62 m. Under the condition of overlying goaf, there was a complete stress structure, which can meet the requirements of suspension support.

To investigate the adsorption properties of methane in coal under low temperatures, the isothermal adsorption tests of the three coal samples with different metamorphic degrees were conducted at the ambient temperatures of 253.15−293.15 K, and the low‐temperature nitrogen adsorption (LNA) tests of coal were also performed. Then a relational expression of equilibrium pressure, temperature, and methane adsorption capacity (T−P model) was deduced to predict the adsorption isotherm at any other temperature based on the Polanyi adsorption theory. The results show that the gas adsorption capacity of coal can be significantly increased at low temperatures (below 273.15 K), and the adsorbed methane in anthracite is obviously more than that in lean coal and coking coal by the virtue of possessing a larger micropore/transition pore volume and specific surface area. The relations between adsorption potential (ε) and adsorption volume (ω) at different temperatures can be drawn on one single logarithmic curve, and a suitable pseudo‐saturation pressure can be obtained by the improved Amankwah's method. The predicted adsorbed capacities via the T−P model are in line with the measured results at other equilibrium conditions, indicating that the model can contribute to the deep coalbed methane resources estimation and the gas disaster prevention and control in coal mines.

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To solve the problem of a rapid attenuation of gas concentration along with drainage borehole collapse in the tectonic coalbeds of South China, a constant pressure grouting technology with inorganic, noncondensable material was proposed. Firstly, the slurry fluidity, water separation rate, and sealing performance of the inorganic sealing materials were tested under different water-cement ratios. The seepage model of slurry in a layer-through borehole was built with COMSOL Multiphysics simulation software, to explore the scopes of loose circles around drainage roadway and borehole, and to analyze the seepage capacity of the slurry under different grouting pressures. Eventually, the sealing performance of the slurry was investigated in the field. The results showed that the inorganic, noncondensable material with the water-cement ratio of 5 : 1 has a strong fluidity, low water retention, high permeability, and good sealing performance. After the excavations of No.2164 drainage roadway and layer-through borehole, there are obvious stress concentrations both at the shoulder corners of the roadway and at the borehole bottom, and the scope of the loose circle around the roadway is about 6.2 m. The effective seepage radius of the inorganic slurry gradually increases with a rising grouting pressure, and the slurry seepage range in the sandstone section is broader than that in the mudstone section. Adopting the constant pressure grouting technology with the slurry, the average drainage concentration of boreholes in Puxi coal mine is 51.5%, and the average gas flow rate is 0.005 m3/min, which are 1.35 times and 1.67 times than those with the cement grouting method.