Biodegradation of azo dyes is difficult due to their complex structures and low BOD to COD ratios. In the present study, the efficiency of using Fenton’s reagent (H2O2 + Fe2+) as a pretreatment process to enhance microbial transformation of reactive black 5 (RB5) in an aqueous system was evaluated. The RB5 with an initial concentration of 250 mg/L was decolorized up to 90% in 60 h by using a bacterial consortium. Fenton’s reagent at a Fe2+ concentration of 0.5 mM and H2O2 concentration of 2.9 mM (molar ratio, 1:5.8) was most effective for decolorization at pH = 3.0. The extent of RB5 removal by the combined Fenton–biotreatment was about 2 times higher than that of biotreatment alone. The production of some aromatic amines intermediates implied partial mineralization of the RB5 in Fenton treatment alone; in addition, decreasing of GC-MS peaks suggested that dearomatization occurred in Fenton-biological process. Fenton pretreatment seems to be a cost–effective option for the biotreatment of azo dyes, due mainly to the lower doses of chemicals, lower sludge generation, and saving of time. Our results demonstrated positive effects of inoculating bacterial consortium which was capable of dye biodegradation with a Fenton’s pretreatment step as well as the benefits of low time required for the biological process. In addition, the potential of field performance of Fenton-biological process because of using bacterial consortium is an other positive effect of it.
In this study, arsenate (As-V) removal using micellar enhanced ultrafiltration (MEUF) modified by cationic surfactants was studied by a dead-end polyacrylonitrile (PAN) membrane apparatus. The UF membrane has been produced by a phase inversion process. The prepared membrane was characterized and analyzed for morphology and membrane properties. The influence of operating parameters such as initial concentrations of As-V, surfactants, pH, membrane thickness, and co-existing anions on the removal of As-V, surfactant rejection, and permeate flux have been studied. The experimental results show that from the two different cationic surfactants used the CPC (cetyl-pyridinium chloride) efficiency (91.7%) was higher than that of HTAB (hexadecyltrimethyl-ammonium bromide) (83.7%). The highest As-V removal was 100%, and was achieved using initial feed concentrations of 100-1000 μg/L , at pH 7 with a membrane thickness of 150 μm in a dead-end filtration system. This efficiency for As-V removal was similar to that obtained using a cross-flow system. Nevertheless, this flux reduction was less than the reduction achieved in the dead-end filtration process. The PAN fabricated membrane in comparison to the RO and NF processes selectively removed the arsenic and the anions, in the water taken from the well, and had no substantial effect on the cations.
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