Syntheses of nanoalloys using diverse experimental methods are reviewed. The main techniques include microwave heating, laser-assisted methods, chemical vapor deposition, and electrochemical methods, as well as a series of chemical reduction and decomposition routes. The nanoalloys possess a series of useful properties, such as magnetic, semiconducting, field-emission materials, that are being applied in the catalytic processes and the creation of optical, electronic, and magnetic materials.

The objective of the present study was to determine levels and calculate ratios of copartition coefficients among organochlorine pesticides β-HCH, pp'DDE, op'DDT and pp'DDT in maternal adipose tissue, maternal blood serum and umbilical blood serum of mother-infant pairs from Veracruz, Mexico. Organochlorine pesticides were analyzed in 70 binomials: maternal adipose tissue, maternal serum and umbilical cord serum samples, using gas chromatography with electron capture detection (GC-ECD). The results were expressed as mg/kg on fat basis. p,p'-DDE was the major organochlorine component, detected in every maternal adipose tissue (0.770 mg/kg), maternal serum sample (5.8 mg/kg on fat basis) and umbilical cord blood sample (6.9 mg/kg on fat basis). p,p'-DDT was detected at 0.101 mg/kg, 2.2 mg/kg and 5.9 mg/kg respectively, according to the order given above. β-HCH was detected at 0.027 mg/kg, 4.2 mg/kg and 28.0 mg/kg respectively. op'DDT was detected only in maternal adipose tissue at 0.011 mg/kg. The copartition coefficients among samples identify significant increases in concentrations from adipose tissue to maternal blood serum and to umbilical blood serum. The increase indicated that maternal adipose tissue released organochlorine pesticides to blood serum and that they are carried over to umbilical cord blood.

Surface functionalization of graphene oxide (GO) is one of the best ways to achieve homogeneous dispersions of GO within polymeric matrices and composites. Nonetheless, studies regarding how the level of GO functionalization affects the macroscopic properties of three-dimensional (3D) printed nanocomposites are still few. Furthermore, the bifunctionalization of GO with the NH 2 /NH 3 + groups to obtain improved thermomechanical macroscopic properties at ultralow loads has not been reported. In this paper, fast and straightforward surface bifunctionalization of GO with a controlled ratio of NH 2 /NH 3 + groups at low, medium, and high functionalization levels (AGOL, AGOM, and AGOH) in a one-step microwave-assisted synthesis is reported for the first time. The functionalization mechanism was disclosed, wherein three graft densities (G φ ) were obtained. A plateau of maximum functionalization (G φ = 4.9 μmol/m 2 = 2.9 molecules/nm 2 ) was reached, suggesting that full coverage of the GO surface is achievable. Also, an increase in the exfoliation of functionalized layers was obtained, ranging from d 002 = 8.6 Å up to d 002 = 15.8 Å. X-ray photoelectron spectroscopy (XPS) reveals the successful functionalization of GO, as well as an atomic relationship NH 2 /NH 3 + of about 50/50% in all functionalized samples. Stereolithographic (SLA) 3D-printed nanocomposites (AGOL/R, AGOM/R, and AGOH/R) were obtained using ultralow loads (0.01 wt %) of each bifunctionalized material. This ultralow amount was sufficient to enhance thermal stability (up to 4 °C) and a significant increase in the glass transition temperature (93 °C ≤ T g ≤ 120 °C). Interestingly, we found that low and medium grafting density promotes a ductile material (ε > 5%); meanwhile, a high graft density produces brittle materials. Also, we observe that the toughness can be tuned as a function of the graft density (AGOH: 24 MPa, AGOM: 342 MPa, AGOL: 562 MPa) at ultralow loadings. The 3D-printed nanocomposites using GO with low graft density (AGOL) increase their tensile strain by 90% in comparison with the control sample (without filler). Finally, the underlying mechanisms were discussed to explain the findings.

The prevalence of heavy metal pollution and mobility of both Pb and Cd was investigated in street dust samples from the Metropolitan Area of Monterrey (MAM) in northern Mexico. Street dust samples from 30 selected sites were analysed for their content of Zn, Cd, Pb, Cr and Ni after digestion according to U.S. EPA Method 3051. Multivariate analysis including correlation coefficient analysis, Principal Component Analysis and Cluster Analysis was used to analyse the data and identify possible sources of these heavy metals. Compared with background values, elevated concentrations of Pb (300 mg kg(-1)), Cd (7.6 mg kg(-1)) and Cr (78 mg kg(-1)) were observed in street dust of MAM. Based on multivariate statistical approaches, the studied elements were classified in three main sources: (1) Cr, Ni and Zn mainly derived from industrial activities; (2) Cd originating from traffic-related activities; and (3) Pb associated with vehicular emissions. A sequential extraction procedure using the Tessier method was applied to evaluate the mobility of Pb and Cd in street dust. The majority of Pb was associated with the residual fraction followed by the carbonate fraction. The majority of Cd was associated with the residual fraction. These results indicated that the mobility was higher in Pb (26%) compared with Cd (11%), posing a potential risk to the environment.

La construcción histórica de la relación entre la naturaleza y el ser humano, pone de manifiesto el proceso dialéctico existente que ahora denominamos medio ambiente y desarrollo. Hoy, esta relación se analiza a través del desarrollo sustentable. Este axioma cuenta con varios puntos de vistas teóricos que pretenden una adecuada relación entre el medio ambiente y el desarrollo, pero además, pretenden orientar el progreso de nuestra sociedad. En el presente trabajo se exhibe su ascenso y definición. PALABRAS CLAVE: DESARROLLO SOSTENIBLE * MEDIO A MBIENTE * DESARROLLO ECONÓMICO * SOCIEDAD ABSTRACTThe historical construction of the relationship between nature and humans, highlighting the dialectical process exists; now, we refer to it like environment and development. Today, this relationship is analyzed through sustainable development. This axiom has several theoretical views, which seeks an appropriate balance between environment and development, but also, aims to guide the progress of our society. In this article, we show its rise and definition.

Key indicatorsSingle-crystal X-ray study T = 298 K Mean (C-C) = 0.002 Å R factor = 0.052 wR factor = 0.167 Data-to-parameter ratio = 16.0For details of how these key indicators were automatically derived from the article, see

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In this work, we report the formation of CuInS 2 thin films on glass substrates by heating chemically deposited multilayers of copper sulfide (CuS) and indium sulfide (In 2 S 3) at 300 and 350 • C in nitrogen atmosphere at 10 Torr. CIS thin films were prepared by varying the CuS layer thickness in the multilayers with indium sulfide. The XRD analysis showed that the crystallographic structure of the CuInS 2 (JCPDS 27-0159) is present on the deposited films. From the optical analysis it was estimated the band gap value for the CIS film (1.49 eV). The electrical conductivity varies from 3 × 10 −8 to 3 −1 cm −1 depending on the thickness of the CuS film. CIS films showed p-type conductivity.