Aluminium alloy Al-Si5Cu3 (319) is one of the most commonly used casting alloys for automobile components, due to its casting characteristics. Iron is the major impurity element that influences the detrimental β-phase formation in secondary aluminum alloys. In the present study, we investigated the influence of the cooling rate on the formation of iron compounds, α-Al 15 (Mn,Fe) 3 Si 2 and β-Fe 5 AlSi phases, in Al-Si5Cu3 containing 1.0% Fe, 0.5% Mn and 0.2% Mg, by thermal analysis and metallography. The results show that the high cooling rates, between 10-10 3 K/s, are able to reduce and nullify the formation of needle-like β-Al5FeSi phase, and help the formation of the Chinese scripts α-Al 15 (Fe,Mn) 3 Si 2 phase. The analysis of the curves reveals that the increase of the cooling rate increases the temperature of nucleation of the α-Al dendrite and decrease the eutectics Al-Si and Al-Cu phases.