Low roll-off angle, high impalement pressure, and mechanical robustness are key requirements for super-liquid-repellent surfaces to realize their potential in applications ranging from gas exchange membranes to protective and self-cleaning materials. Achieving these properties is still a challenge with superamphiphobic surfaces, which can repel both water and low-surface-tension liquids. In addition, fabrication procedures of superamphiphobic surfaces are typically slow and expensive. Here, by making use of liquid flame spray, a silicon dioxide-titanium dioxide nanostructured coating is fabricated at a high velocity up to 0.8 m s . After fluorosilanization, the coating is superamphiphobic with excellent transparency and an extremely low roll-off angle; 10 µL drops of n-hexadecane roll off the surface at inclination angles even below 1°. Falling drops bounce off when impacting from a height of 50 cm, demonstrating the high impalement pressure of the coating. The extraordinary properties are due to a pronounced hierarchical nanotexture of the coating.
Surface engineering can be used to prevent ice accumulation and adhesion in environments that deal with icing problems. One recent engineering approach, slippery liquid infused porous surfaces (SLIPS), comprises a smooth and slippery lubricating surface, where lubricant is trapped within the pores of a solid material to repel various substances, such as water and ice. However, it remains unclear whether the slippery surfaces retain their icephobic characteristics under the impact of supercooled water droplets or repeated freezing and melting cycles. Here, the icephobic properties of SLIPS are evaluated under multiple droplet freeze–thaw and ice accretion–detachment cycles and compared to hydrophobic and superhydrophobic surfaces. The experiments are designed to mimic real environmental conditions, thus, the icephobicity is investigated in icing wind tunnel, where ice accretion occurs through the impact of supercooled water droplets. The adhesion of ice remained extremely low, <10 kPa, which is four times lower than ice adhesion onto smooth fluoropolymer surfaces, even after repeated ice accretion–detachment cycles. Moreover, cyclic droplet freeze–thaw experiments provide insight into the effects of temperature cycling on SLIPS wettability, showing stable wetting performance. The results suggest liquid infused porous surfaces as a potential solution to icephobicity under challenging and variating environmental conditions.
Slippery, liquid-infused porous surfaces offer a promising route for producing omniphobic and anti-icing surfaces. Typically, these surfaces are made as a coating with expensive and time consuming assembly methods or with fluorinated films and oils. We report on a route for producing liquid-infused surfaces, which utilizes a liquid precursor fed oxygen-hydrogen flame to produce titania nanoparticles deposited directly on a low-density polyethylene film. This porous nanocoating, with thickness of several hundreds of nanometers, is then filled with silicone oil. The produced surfaces are shown to exhibit excellent anti-icing properties, with an ice adhesion strength of ∼12 kPa, which is an order of magnitude improvement when compared to the plain polyethylene film. The surface was also capable of maintaining this property even after cyclic icing testing.
TiO2 inverse opal (TIO) structures were prepared by the conventional wet chemical method, resulting in well-formed structures for photocatalytic activity. The obtained structures were functionalized with liquid flame spray-deposited silver nanoparticles (AgNPs). The nanocomposites of TIO and AgNPs were extensively characterized by various spectroscopies such as UV, Raman, X-ray diffraction, energy-dispersive spectroscopy, and X-ray photoelectron spectroscopy combined with microscopic methods such as scanning electron microscopy, transmission electron microscopy (TEM), and high-resolution TEM. The characterization confirmed that high-quality heterostructures had been fabricated with evenly and uniformly distributed AgNPs. Fabrication of anatase TiO2 was confirmed, and formation of AgNPs was verified with surface plasmon resonant properties. The photocatalytic activity results measured in the gas phase showed that deposition of AgNPs increases photocatalytic activity both under UVA and visible light excitation; moreover, enhanced hydrogen evolution was demonstrated under visible light.
Iron oxide nanoparticles were synthesized in a liquid flame spray process from iron(III) nitrate. The choice of chemicals and all other process parameters affects the crystallographic phase composition and the quality of the material. Adjustment of the solvent composition and the gas flow rates was used to control the phase composition of the produced particles. All samples consisted of pure maghemite (γ-Fe 2 O 3 ) or a mixture of maghemite and hematite (α-Fe 2 O 3 ). When using pure alcohols as solvents, the maghemite/hematite phase ratio could be adjusted by changing the equivalence ratio that describes the oxidation conditions in the flame zone. A large residual particle mode formed in the size range of ~20-700 nm along with a dominant very fine particle mode (2-8 nm). Both phases seemed to contain large particles. A partial substitution of methanol with carboxylic acids turned the hematite phase into maghemite completely, even though some of particles were possibly not fully crystallized.Residual particles were still present, but their size and number could be decreased by raising the heat of combustion of the precursor solution. 30 vol-% substitution of methanol with 2-ethylhexanoic acid was adequate to mostly erase the large particles. K E Y W O R D Siron/iron compounds, liquid flame spray, nanoparticles, synthesis
The quality of aerosol‐produced nanopowders can be impaired by micron‐sized particles formed due to non‐uniform process conditions. Methods to evaluate the quality reliably and fast, preferably on‐line, are important at industrial scales. Here, aerosol analysis methods are used to determine the fractions of nanoparticles and micron‐sized residuals from poorly volatile precursors. This is accomplished using aerosol instruments to measure the number and mass size distributions of Liquid Flame Spray‐generated alumina and silver particles produced from metal nitrates dissolved in ethanol and 2‐ethylhexanoic acid (EHA). The addition of EHA had no effect on silver, whereas, 5% EHA concentration was enough to shift the alumina mass from the residuals to nanoparticles. The size‐resolved aerosol analysis proved to be an effective method for determining the product quality. Moreover, the used on‐line techniques alone can be used to evaluate the process output when producing nanopowders, reducing the need for tedious off‐line analyses. © 2016 American Institute of Chemical Engineers AIChE J, 63: 881–892, 2017
Particle emissions and secondary aerosol formation from internal combustion engines deteriorate air quality and significantly affect human wellbeing and health. Both the direct particle emissions and the emissions of compounds contributing to secondary aerosol formation depend on choices made in selecting fuels, engine technologies, and exhaust aftertreatment (EAT). Here we study how catalytic EATs, particle filtration, and fuel choices affect these emissions concerning heavy-duty diesel engine. We observed that the most advanced EAT decreased the emissions of fresh exhaust particle mass as much as 98% (from 44.7 to 0.73 mg/kWh) and the formation of aged exhaust particle mass ∼100% (from 106.2 to ∼0 mg/kWh). The composition of emitted particles depended significantly on the EAT and oxidative aging. While black carbon typically dominated the composition of fresh exhaust particles, aged particles contained more sulfates and organics. The fuel choices had minor effects on the secondary aerosol formation, implicating that, in diesel engines, either the lubricant is a significant source of secondary aerosol precursors or the precursors are formed in the combustion process. Results indicate that the utilization of EAT in diesel engines would produce benefits with respect to exhaust burden on air quality, and thus their utilization should be promoted especially in geographical areas suffering from poor air quality.
In this review article, a specific flame spray pyrolysis method, Liquid Flame Spray (LFS), is introduced to produce nanoparticles using a coflow type hydrogen-oxygen flame utilizing pneumatically sprayed liquid precursor. This method has been widely used in several applications due to its characteristic features, from producing nanopowders and nanostructured functional coatings to colouring of art glass and generating test aerosols. These special characteristics will be described via the example applications where the LFS has been applied in the past 20 years.
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