Figure S1. Acquired and calculated powder XRD patterns of Li 0.8 Fe(H 2 O) 2 [BP 2 O 8 ]•H 2 O.Figure S2. FT-IR spectra of Li 0.8 Fe(H 2 O) 2 [BP 2 O 8 ]•H 2 O and its chemically oxidized phase.
Multiple environment mechanical testing of solid‐oxide fuel cells (SOFCs) and SOFC materials is critical to ensure appropriate compressive sealing in stack designs. Establishing the effects of temperature, environment, and porosity on the flexural strength of ceria‐based SOFCs is a significant step toward practical deployment of the technology. This article presents research into these properties by use of a temperature and atmosphere controlled 3‐point bend fixture capable of reaching Intermediate Temperature (IT)‐SOFC operating conditions (650°C). Gadolinium‐doped ceria (GDC) samples with varying porosity and pore geometry were tested and it was determined that more spherical porosity contributed to improved flexural strength as compared with higher aspect ratio porosity. A linear strengthening effect was also observed with increasing temperature from ambient to 650°C for GDC‐based anode support layers and half‐cell samples. Scanning electron microscopy was performed on fracture surfaces to identify fracture modes and to examine internal pore structures. Directionality of the applied stress with respect to the layered microstructure was found to have no measurable impact on mechanical properties in air, but orientation had a significant impact on strength of cells with reduced anodes. Additionally, with the support of thermogravimetric analysis, it was determined that after reduction, exposure to oxygen below 100°C does not influence mechanical properties of the cells.
Solid‐oxide fuel cells (SOFCs) have the potential to increase electricity generation efficiency, but traditional SOFCs supported by nickel cermets suffer from reliability challenges due to weaker mechanical strength caused by cracking after redox cycling. To solve this problem, a new ceramic anode material, SrFe0.2Co0.4Mo0.4O3−δ (SFCM) combined with Ce0.9Gd0.1O2 (GDC), was evaluated for conductivity and mechanical strength at SOFC operating conditions and after redox cycling. Fracture toughness of SFCM was determined to be (0.124 ± 0.023) MPa√m at room temperature in air, increasing to (0.286 ± 0.038) MPa√m at 600°C. A mixture of SFCM:GDC showed fracture toughness between the two materials, following SFCM's trend with temperature. The SFCM‐GDC anode supported half‐cell strength increases by 31% from room temperature to 600°C as intrinsic stresses remaining from sintering are relaxed and thermal expansion pushes existing cracks closed. Exposure to reducing gasses decreases strength by 29% compared to ambient, due to oxygen vacancy formation and microstructural flaw changes. It is found that SFCM‐GDC based cells tolerate cycling well because of phase stability but weaken from 34.3 to 22.4 MPa due to uniform growth of critical microstructural flaws.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.