The shape-memory epoxy (SME) mixed with 10 wt % polycaprolactone (PCL) microspheres containing 5% cerium(III) nitrate (Ce(NO 3 ) 3 ) (PCL5Ce) was coated on an aluminum plate 2024-T3 to investigate the self-healing property. The coating was scratched and heated at 80 °C for 30 min to activate the self-healing mechanism and compare with a nonscratched coating. Surface morphology was investigated by scanning electron microscopy. The scratch was completely healed by the PCL5Ce via a thermally assisted self-healing process. Based on electrochemical impedance spectroscopy, the postheated scratched coating had shown impedance values close to the nonscratched coating, which indicated that corrosion resistivity was restored. Ce(NO 3 ) 3 content at the scratched area was analyzed by focused ion beam–scanning electron microscopy. The scratch width was healed and filled with Ce(NO 3 ) 3 . Therefore, PCL5Ce is capable of being used as an enhancing additive for the self-healing performance in SME coating.

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