We have measured, using electron spectroscopy, the lowest-energy doubly hollow lithium triply excited (3l3lЈ3lЉ) 2 P state. Energies, widths, and partial cross sections have been measured and calculated using the saddle-point technique and the R-matrix approximation. Our results show good agreement between experimental and theoretical data for the energy and the width of the doubly hollow state. ͓S1050-2947͑97͒50408-2͔PACS number͑s͒: 32.80. Hd, 32.80.Fb In a hollow atomic or ionic state, the first inner shell ͑the K shell͒ is empty. Correlation effects can produce simultaneous excitation of all three electrons in lithium atoms and create hollow lithium states of the type (nlnЈlЈnЉlЉ) with nу2. After the first observation of the lowest-energy triply excited state ͓1͔, several experiments involving the use of photoion ͓2-4͔ and photoelectron ͓5-8͔ spectrometries have contributed to provide the energies of a number of (nlnЈlЈnЉlЉ) states with at least one of n, nЈ, or nЉ equal to 2, as well as the partial cross sections for photoionization of atomic lithium into various (nlnЈlЈ) final states of the Li ϩ ion (nϭ1 or 2, nЈу2). Several Rydberg series have been measured and identified in the many observed hollow lithium states ͓8,9͔. Theoretical calculations using the R-matrix approximation have provided results for the partial photoionization cross sections ͓5-9͔ that are generally in very good agreement with the experimental data, whereas the saddlepoint technique ͓10-12͔ has given very accurate calculations of the energies of a number of hollow lithium states, sometimes within one or two hundredths of an eV of the measured values.The demands on theoretical and experimental techniques increase at higher photon energies, for which triply excited states with all three electrons having principal quantum numbers equal to 3 or above can be created. We propose the name doubly hollow state for a triply excited state in which both K and L shells are empty. All n, nЈ, and nЉ have values that are higher than 2 for such a triply excited (nlnЈlЈnЉlЉ) state. An earlier report on an experiment with ion detection in the Li 2ϩ channel ͓4͔ mentioned some analogous features, but no data were shown at that time. Following submission of the present work, we received an article ͓13͔ in which one figure shows a profile of the first (3l,3lЈ,3lЉ) state recorded in the Li 2ϩ ionic channel. At excitation energies higher than the lowest doubly excited 2s 2 1 S Li ϩ limit ͑151.66 eV͒, triply excited states can decay to either singly or doubly excited states of the Li ϩ ion. Decay path into (1snl) Li ϩ ionic states causes interferences with the direct photoionization route as reported earlier ͓5,6͔. Decay to doubly excited (2l2lЈ) Li ϩ ionic states produces emission of a low-energy electron. This Li ϩ state subsequently decays to the ground state of the doubly charged Li 2ϩ ion, with emission of a high-energy electron. By measuring the photon-energy dependence of the intensity of these high-energy electrons, one determines a partial cross sec...