Context. The inner regions of the envelopes surrounding young protostars are characterised by a complex chemistry, with prebiotic molecules present on the scales where protoplanetary disks eventually may form. The Atacama Large Millimeter/submillimeter Array (ALMA) provides an unprecedented view of these regions zooming in on Solar System scales of nearby protostars and mapping the emission from rare species. Aims. The goal is to introduce a systematic survey, "Protostellar Interferometric Line Survey (PILS)", of the chemical complexity of one of the nearby astrochemical templates, the Class 0 protostellar binary IRAS 16293−2422, using ALMA, to understand the origin of the complex molecules formed in its vicinity. In addition to presenting the overall survey, the analysis in this paper focuses on new results for the prebiotic molecule glycolaldehyde, its isomers and rarer isotopologues and other related molecules.Methods. An unbiased spectral survey of IRAS 16293−2422 covering the full frequency range from 329 to 363 GHz (0.8 mm) has been obtained with ALMA, in addition to a few targeted observations at 3.0 and 1.3 mm. The data consist of full maps of the protostellar binary system with an angular resolution of 0.5 (60 AU diameter), a spectral resolution of 0.2 km s −1 and a sensitivity of 4-5 mJy beam −1 km s −1 -approximately two orders of magnitude better than any previous studies. Results. More than 10,000 features are detected toward one component in the protostellar binary, corresponding to an average line density of approximately one line per 3 km s −1 . Glycolaldehyde, its isomers, methyl formate and acetic acid, and its reduced alcohol, ethylene glycol, are clearly detected and their emission well-modeled with an excitation temperature of 300 K. For ethylene glycol both lowest state conformers, aGg and gGg , are detected, the latter for the first time in the ISM. The abundance of glycolaldehyde is comparable to or slightly larger than that of ethylene glycol. In comparison to the Galactic Center these two species are over-abundant relative to methanol, possibly an indication of formation of the species at low temperatures in CO-rich ices during the infall of the material toward the central protostar. Both 13 C and deuterated isotopologues of glycolaldehyde are detected, also for the first time ever in the ISM. For the deuterated species a D/H ratio of ≈5% is found with no differences between the deuteration in the different functional groups of glycolaldehyde, in contrast to previous estimates for methanol and recent suggestions of significant equilibration between water and -OH functional groups at high temperatures. Measurements of the 13 C-species lead to a 12 C: 13 C ratio of ≈30, lower than the typical ISM value. This low ratio may reflect an enhancement of 13 CO in the ice due to either ion-molecule reactions in the gas before freeze-out or differences in the temperatures where 12 CO and 13 CO ices sublimate. Conclusions. The results reinforce the importance of low temperature grain surfac...

Formamide (NH 2 CHO) has previously been detected in several star-forming regions and is thought to be a precursor for different prebiotic molecules. Its formation mechanism is still debated, however. Observations of formamide, related species, and their isopotologues may provide useful clues to the chemical pathways leading to their formation. The Protostellar Interferometric Line Survey (PILS) represents an unbiased, high angular resolution and sensitivity spectral survey of the low-mass protostellar binary IRAS 16293-2422 with the Atacama Large Millimeter/submillimeter Array (ALMA). For the first time, we detect the three singly deuterated forms of NH 2 CHO (NH 2 CDO, cis-and trans-NHDCHO), as well as DNCO towards the component B of this binary source. The images reveal that the different isotopologues are all present in the same region. Based on observations of the 13 C isotopologues of formamide and a standard 12 C/ 13 C ratio, the deuterium fractionation is found to be similar for the three different forms with a value of about 2%. The DNCO/HNCO ratio is also comparable to the D/H ratio of formamide (∼1%). These results are in agreement with the hypothesis that NH 2 CHO and HNCO are chemically related through grain-surface formation.

Young stars are associated with prominent outflows of molecular gas. The ejection of gas is believed to remove angular momentum from the protostellar system, permitting young stars to grow by the accretion of material from the protostellar disk. The underlying mechanism for outflow ejection is not yet understood, but is believed to be closely linked to the protostellar disk. Various models have been proposed to explain the outflows, differing mainly in the region where acceleration of material takes place: close to the protostar itself ('X-wind', or stellar wind), in a larger region throughout the protostellar disk (disk wind), or at the interface between the two. Outflow launching regions have so far been probed only by indirect extrapolation because of observational limits. Here we report resolved images of carbon monoxide towards the outflow associated with the TMC1A protostellar system. These data show that gas is ejected from a region extending up to a radial distance of 25 astronomical units from the central protostar, and that angular momentum is removed from an extended region of the disk. This demonstrates that the outflowing gas is launched by an extended disk wind from a Keplerian disk.

The evolutionary past of our Solar system can be pieced together by comparing analogous lowmass protostars with remnants of our Protosolar Nebula-comets. Sulphur-bearing molecules may be unique tracers of the joint evolution of the volatile and refractory components. ALMA Band 7 data from the large unbiased Protostellar Interferometric Line Survey are used to search for S-bearing molecules in the outer disc-like structure, ∼60 au from IRAS 16293-2422 B, and are compared with data on 67P/Churyumov-Gerasimenko (67P/C-G) stemming from the ROSINA (Rosetta Orbiter Spectrometer for Ion and Neutral Analysis) instrument aboard Rosetta. Species such as SO 2 , SO, OCS, CS, H 2 CS, H 2 S, and CH 3 SH are detected via at least one of their isotopologues towards IRAS 16293-2422 B. The search reveals a first-time detection of OC 33 S towards this source and a tentative first-time detection of C 36 S towards a low-mass protostar. The data show that IRAS 16293-2422 B contains much more OCS than H 2 S in comparison to 67P/C-G; meanwhile, the SO/SO 2 ratio is in close agreement between the two targets. IRAS 16293-2422 B has a CH 3 SH/H 2 CS ratio in range of that of our Solar system (differences by a factor of 0.7-5.3). It is suggested that the levels of UV radiation during the initial collapse of the systems may have varied and have potentially been higher for IRAS 16293-2422 B due to its binary nature; thereby, converting more H 2 S into OCS. It remains to be conclusively tested if this also promotes the formation of S-bearing complex organics. Elevated UV levels of IRAS 16293-2422 B and a warmer birth cloud of our Solar system may jointly explain the variations between the two low-mass systems.

The growth of dust grains in protoplanetary disks is a necessary first step towards planet formation 1 . This growth has been inferred via observations of thermal dust emission 2 towards mature protoplanetary systems (age > 2 million years) with masses that are, on average, similar to Neptune 3 . In contrast, the majority of confirmed exoplanets are heavier than Neptune 4 . Given that young protoplanetary disks are more massive than their mature counterparts, this suggests that planet formation starts early, but evidence for grain growth that is spatially and temporally coincident with a massive reservoir in young disks remains scarce. Here, we report observations on a lack of emission of carbon monoxide isotopologues within the inner ∼15 au of a very young (age ∼100,000 years) disk around the Solar-type 1 arXiv:1806.09649v1 [astro-ph.SR]

Context.One of the open questions in astrochemistry is how complex organic and prebiotic molecules are formed. The unsurpassed sensitivity of the Atacama Large Millimeter/submillimeter Array (ALMA) takes the quest for discovering molecules in the warm and dense gas surrounding young stars to the next level. Aims. Our aim is to start the process of compiling an inventory of oxygen-bearing complex organic molecules toward the solar-type Class 0 protostellar binary IRAS 16293-2422 from an unbiased spectral survey with ALMA, Protostellar Interferometric Line Survey (PILS). Here we focus on the new detections of ethylene oxide (c-C 2 H 4 O), acetone (CH 3 COCH 3 ), and propanal (C 2 H 5 CHO). Methods. With ALMA, we surveyed the spectral range from 329 to 363 GHz at 0.5 (60 AU diameter) resolution. Using a simple model for the molecular emission in local thermodynamical equilibrium, the excitation temperatures and column densities of each species were constrained. Results. We successfully detect propanal (44 lines), ethylene oxide (20 lines) and acetone (186 lines) toward one component of the protostellar binary, IRAS16293B. The high resolution maps demonstrate that the emission for all investigated species originates from the compact central region close to the protostar. This, along with a derived common excitation temperature of T ex ≈ 125 K, is consistent with a coexistence of these molecules in the same gas. Conclusions. The observations mark the first detections of acetone, propanal and ethylene oxide toward a low-mass protostar. The relative abundance ratios of the two sets of isomers, a CH 3 COCH 3 /C 2 H 5 CHO ratio of 8 and a CH 3 CHO/c-C 2 H 4 O ratio of 12, are comparable to previous observations toward high-mass protostars. The majority of observed abundance ratios from these results as well as those measured toward high-mass protostars are up to an order of magnitude above the predictions from chemical models. This may reflect either missing reactions or uncertain rates in the chemical networks. The physical conditions, such as temperatures or densities, used in the models, may not be applicable to solar-type protostars either.

Context. Through spectrally unresolved observations of high-J CO transitions, Herschel Photodetector Array Camera and Spectrometer (PACS) has revealed large reservoirs of warm (300 K) and hot (700 K) molecular gas around low-mass protostars. The excitation and physical origin of this gas is still not understood. Aims. We aim to shed light on the excitation and origin of the CO ladder observed toward protostars, and on the water abundance in different physical components within protostellar systems using spectrally resolved Herschel Heterodyne Instrument for the Far Infrared (HIFI) data. Methods. Observations are presented of the highly excited CO line J = 16-15 (E up /k B = 750 K) with Herschel-HIFI toward a sample of 24 low-mass protostellar objects. The sources were selected from the Herschel "Water in Star-forming regions with Herschel" (WISH) and "Dust, Ice, and Gas in Time" (DIGIT) key programs. that is often offset from the source velocity. Some sources show other velocity components such as extremely-high-velocity features or "bullets". All these velocity components were first detected in H 2 O line profiles. The average rotational temperature over the entire profile, as measured from comparison between CO J=16-15 and 10-9 emission, is ∼ 300 K. A radiative-transfer analysis shows that the average H 2 O/CO column-density ratio is ∼0.02, suggesting a total H 2 O abundance of ∼2×10 −6, independent of velocity. Conclusions. Two distinct velocity profiles observed in the HIFI line profiles suggest that the high-J CO ladder observed with PACS consists of two excitation components. The warm PACS component (300 K) is associated with the broad HIFI component, and the hot PACS component (700 K) is associated with the offset HIFI component. The former originates in either outflow cavity shocks or the disk wind, and the latter in irradiated shocks. The low water abundance can be explained by photodissociation. The ubiquity of the warm and hot CO components suggests that fundamental mechanisms govern the excitation of these components; we hypothesize that the warm component arises when H 2 stops being the dominant coolant. In this scenario, the hot component arises in cooling molecular H 2 -poor gas just prior to the onset of H 2 formation. High spectral resolution observations of highly excited CO transitions uniquely shed light on the origin of warm and hot gas in low-mass protostellar objects.

Organohalogens, a class of molecules that contain at least one halogen atom bonded to carbon, are abundant on Earth where they are mainly produced through industrial and biological processes [1]. Consequently, they have been proposed as biomarkers in the search for life on exoplanets [2]. Simple halogen hydrides have been detected in interstellar sources and in comets, but the presence and possible incorporation of more complex halogen-containing molecules such as organohalogens into planet-forming regions is uncertain [3, 4]. Here we report the first interstellar detection of two isotopologues of the organohalogen CH 3 Cl and put some constraints on CH 3 F in the gas surrounding the low-mass protostar IRAS 16293-2422, using the Atacama Large Millimeter/submillimeter Array (ALMA). We also find CH 3 Cl in the coma of comet 67P/Churyumov-Gerasimenko (67P/C-G) using the Rosetta Orbiter Spectrometer for Ion and Neutral Analysis (ROSINA) instrument. The detections reveal an efficient pre-planetary formation pathway of organohalogens. Cometary impacts may deliver these species to young planets and should thus be included as a potential abiotical production source when interpreting future organohalogen detections in atmospheres of rocky planets.