“…The ALMA Protostellar Interferometric Line Survey 1 (PILS, Jørgensen et al 2016) performed an unbiased spectral survey of the system in Band 7, demonstrating the strength of ALMA for detecting new complex species towards the most compact component IRAS 16293B of the system, including CH 3 Cl (Fayolle et al 2017), CH 3 NC (Calcutt et al 2018a), HONO (Coutens et al 2019), NH 2 CN (Coutens et al 2018), and CH 3 NCO (Ligterink et al 2017). In addition, many deuterated and less abundant isotopologues have been found for the first time in the interstellar medium (ISM) towards this source, including NHDCHO, NH 2 CDO , NHDCN (Coutens et al 2018), CHD 2 CN (Calcutt et al 2018b), deuterated and 13 C isotopologues of CH 2 OHCHO, deuterated ethanol (C 2 H 5 OH), ketene (CH 2 CO), acetaldehyde (CH 3 CHO) and formic acid (HCOOH) , OC 33 S 1 The reduced dataset and all the publications are available on the website http://youngstars.nbi.dk/PILS/ (Drozdovskaya et al 2018), and doubly deuterated methyl formate (CHD 2 OCHO; Manigand et al 2018). This paper aims to study the O-bearing COMs in the other protostar IRAS 16293A of the binary system and to compare their abundances with IRAS 16293B.…”