Oxide-based metal-insulator-metal structures are of special interest for future resistive random-access memories. In such cells, redox processes on the nanoscale occur during resistive switching, which are initiated by the reversible movement of native donors, such as oxygen vacancies. The formation of these fi laments is mainly attributed to an enhanced oxygen diffusion due to Joule heating in an electric fi eld or due to electrical breakdown. Here, the development of a dendrite-like structure, which is induced by an avalanche discharge between the top electrode and the Ta 2 O 5-x layer, is presented, which occurs instead of a local breakdown between top and bottom electrode. The dendrite-like structure evolves primarily at structures with a pronounced interface adsorbate layer. Furthermore, local conductive atomic force microscopy reveals that the entire dendrite region becomes conductive. Via spectromicroscopy it is demonstrated that the subsequent switching is caused by a valence change between Ta 4+ and Ta 5+ , which takes place over the entire former Pt/Ta 2 O 5-x interface of the dendrite-like structure.
A portable device using the SAW-based impedance sensor type based on one interdigital transducer simultaneously as SAW generator and sensor element (1-port approach) is introduced. As a novelty, the so far required expensive vector network analyzer (VNA) is replaced by a hand-held device to measure the impedance spectrum of the SAW sensor by RF-gain-phase meters. Hence, some of the best features from the conventional oscillator and VNA approaches are combined to develop a low-cost and self-contained measurement system, including signal in- and output ability for real-time measurements. The pivotal aspect of the portable system is the transfer of the sophisticated high frequency approach into a quasi-static one. This enables the use of simple lumped electronics without the need of impedance matching circuits. Proof-of-concept was carried out by measuring conductivities of phosphate-buffered solutions and viscosities of glycerin. Sensitivities for temperature of 0.3%/°C, viscosity of 10.1% (mPa s)−1 and conductivity of 0.5% (S cm)−1 have been determined, respectively, which are competitive results compared to the benchmark approaches.
All actually used SAW sensors have in common that they analyze the transmission characteristics of propagating SAWs. Here, a portable device using the SAW-based impedance sensor type based on one interdigital transducer (IDT) simultaneously as SAW generator and sensor element (1-port approach) is presented. The input port reflection coefficient S11 is measured at the IDT instead of the commonly used S21 transmission forward gain parameter. As a novelty, the so far required expensive vector network analyzer (VNA) is replaced by a hand-held device to measure the impedance spectrum of the SAW sensor by RF-gain-phase meters. The pivotal aspect of the portable system is the transfer of the sophisticated high frequency approach into a quasi-static one. This enables the use of simple lumped electronics without the need of impedance matching circuits. Proof-of-concept was carried out by measuring conductivities of phosphate-buffered solutions (PBS) and viscosities of glycerin. Sensitivities for conductivity of 64 Hz/S cm −1 and for viscosity of 122 mΩ/mPas were obtained, respectively.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.