For three-dimensional (3D) metal-organic frameworks (MOFs), the presence and nature of structural defects has been recognized as a key factor shaping the material's physical and chemical behavior. In this work, the formation of the "missing linker" defects has been addressed in the model biphenyl-4,4'-dicarboxylate (bpdc)-based Zr MOF, UiO-67. The defect showed strong dependence on the nature of the modulator acid used in the MOF synthesis; the defects, in turn, were found to correlate with the MOF physical and chemical properties. The dynamic nature of the Zr6 (node)-monocarboxylate bond showed promise in defect functionalization and "healing", including the formation of X-ray-quality "defect-free" UiO-67 single crystals. Chemical transformations at defect sites have also been explored. The study was also extended to the isoreticular UiO-66 and UiO-68' systems.
A metal–organic framework
(MOF) with high volumetric deliverable
capacity for methane was synthesized after being identified by computational
screening of 204 hypothetical MOF structures featuring (Zr6O4)(OH)4(CO2)n inorganic
building blocks. The predicted MOF (NU-800) has an fcu topology in which zirconium nodes are connected via ditopic
1,4-benzenedipropynoic acid linkers. Based on our computer simulations,
alkyne groups adjacent to the inorganic zirconium nodes provide more
efficient methane packing around the nodes at high pressures. The
high predicted gas uptake properties of this new MOF were confirmed
by high-pressure isotherm measurements over a large temperature and
pressure range. The measured methane deliverable capacity of NU-800 between 65 and 5.8 bar is 167 cc(STP)/cc (0.215 g/g),
the highest among zirconium-based MOFs. High-pressure uptake values
of H2 and CO2 are also among the highest reported.
These high gas uptake characteristics, along with the expected highly
stable structure of NU-800, make it a promising material
for gas storage applications.
We successfully demonstrate an approach based on linker fragmentation to create defects and tune the pore volumes and surface areas of two metal-organic frameworks, NU-125 and HKUST-1, both of which feature copper paddlewheel nodes. Depending on the linker fragment composition, the defect can be either a vacant site or a functional group that the original linker does not have. In the first case, we show that both surface area and pore volume increase, while in the second case they decrease. The effect of defects on the high-pressure gas uptake is also studied over a large temperature and pressure range for different gases. We found that despite an increase in pore volume and surface area in structures with vacant sites, the absolute adsorption for methane decreases for HKUST-1 and slightly increases for NU-125. However, the working capacity (deliverable amount between 65 and 5 bar) in both cases remains similar to parent frameworks due to lower uptakes at low pressures. In the case of NU-125, the effect of defects became more pronounced at lower temperatures, reflecting the greater surface areas and pore volumes of the altered forms.
We designed, synthesized, and characterized a new Zr-based metal-organic framework material, NU-1100, with a pore volume of 1.53 ccg(-1) and Brunauer-Emmett-Teller (BET) surface area of 4020 m(2) g(-1) ; to our knowledge, currently the highest published for Zr-based MOFs. CH4 /CO2 /H2 adsorption isotherms were obtained over a broad range of pressures and temperatures and are in excellent agreement with the computational predictions. The total hydrogen adsorption at 65 bar and 77 K is 0.092 g g(-1) , which corresponds to 43 g L(-1) . The volumetric and gravimetric methane-storage capacities at 65 bar and 298 K are approximately 180 vSTP /v and 0.27 g g(-1) , respectively.
Zr-MOF synthesis modulated by various amino acids, including L-proline, glycine and L-phenylalanine is shown as a straightforward approach towards functional group incorporation and particle size control. High yields in Zr-MOF are achieved employing 5 equiv of the modulator at 120 o C; at lower temperatures, the method provides a series of Zr-MOFs with increased particle size, including many suitable for single crystal X-Ray diffraction. Furthermore, amino acid modulators can be incorporated at defect sites of Zr-MOFs with up to 1:1 amino acid-to-strut ratio, depending on the ligand structure and reaction conditions. The MOFs obtained through amino acid modulation exhibit improved CO2 capture capacity when compared to non-functionalized material.
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