The process of non-reagent adjustment of the pH of a NaCl solution (0.5 g/L) of different acidity was investigated by the method of bipolar electrodialysis on a device operating according to the K-system (concentration). The experiments were carried out in the range pH = 2.0–12.0 with monopolar cation-exchange MK-40 (for alkaline solutions) or anion-exchange MA-40 (for acidic solutions) and bipolar MB-2 membranes. The regularities of the change in the pH of the solution on the current density, process productivity and energy consumption for the neutralization process have been investigated. Revealed: with different productivity of the apparatus (Q = 0.5–1.5 m3/h), in the range of pH 3.0–11.0, with an increase in the current density, a neutral pH value is achieved. It has been shown that at pH above 11.0 and below 3.0, even at high current densities (i > 20 A/m2), its value cannot be changed. This is due to the neutralization of the H+ or OH− ions generated by the bipolar membrane by water ions, which are formed as a result of the dissociation of water molecules at the border of the monopolar membrane and the solution under conditions when the value of current exceeds the limiting value.
The widespread use of surfactants increasingly requires the development and application of reliable methods for the demineralization of wastewaters, preventing environmental pollution. One of the most reliable and effective methods of demineralization of wastewaters is the electrodialysis method. Studying the behavior of large organic ions in the membrane is important for modeling cell membranes and purification of medicinal and biological preparations. The sorption characteristics of the MA-40 and MK-40 ion-exchange membranes in solutions of simple and organic electrolytes, and in a solution of the surfactant were investigated. It was found that the sorption of organic ions by membranes is mainly of an ion-exchange nature. The moisture content and elasticity of the membranes decreases in solutions of organic electrolytes, during the sorption of which the membrane becomes brittle. A study showed that in the solutions of organic electrolytes, the MA-40 membrane retains high electrochemical activity, while the MK-40 in a solution of the surfactant completely loses it. From the data obtained in this work, it is shown that organic ions do not present а hazard when water is desalted by electrodialysis, whereas sorption of surfactant ions leads to membrane poisoning.
The problem of substantiation of methodological bases of radio resource management of military radio communication systems in the conditions of a priori uncertainty is solved in the work. The object of research is the military radio communication system. One of the most problematic places in the management of military radio resources is the inability to carry out a hierarchical management of the parameters and modes of operation of both individual radios and the military radio system as a whole. This reduces the efficiency of the system itself and the efficiency of its application.
The scientific problem is solved by substantiating the methodological principles of radio resource management of military radio communication systems in conditions of a priori uncertainty. During the research, the authors used the main provisions of the theory of queuing, the theory of automation, the theory of complex technical systems, as well as general scientific methods of cognition, namely analysis and synthesis. The novelty is that in the course of work:
– the purpose of functioning of an operative management subsystem of a radio resource of military radio communication systems is formulated;
– indicators and criteria of functioning efficiency of military radio communication systems are determined;
– decomposition of the solution of this problem into problems depending on the signal and noise situation is carried out.
An approach based on the hierarchical decomposition of the functional structure of networks, the behavior of which is described by stochastic differential (or difference) equations of the high dimension state, into a number of interconnected but simpler functional structures is used for the functional description of military radio communication systems. It will allow to make a decomposition of the state of the military radio system and increase the efficiency of decision-making on adjusting the modes of operation and parameters of the military radio system in real time. The research results should be used at the stage of operational management of parameters and modes of these systems operation.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.