More than three years of pilot-plant operation has documented that inhibition of nitrification was found to influence the dimensioning of the largest Danish wastewater treatment plant, which serves a major part of Copenhagen. Hence, a program for investigating the sources of substances inhibitory to nitrification was initiated. Since the number of substances potentially inhibitory to nitrification is very high, the investigations used direct testing of inhibitory effects on nitrification as a tool for the mapping operations. The overall purpose of the investigation was to determine the types of sources of inhibitory substances and to suggest a program for source control to be implemented by the individual municipalities in the catchment area. This paper describes the strategy for sampling and the results of the first two years of activity. Major conclusions have been that the most important sources of inhibitory substances are to be found among the industries, and that nearly all of the industries investigated exhibited some kind of inhibitory effect Further, is was demonstrated that the toxic unit calculation might be used in the quantification of the sources, and that the observed effects could be explained by the chemical substances in the wastewater from the industries. Based on the above described results, a strategy for control of the inhibitory effects at the different levels of the catchment area was suggested.
The objective of the work presented is to demonstrate how computer based models can be used to improve the effluent quality from wastewater treatment plants by optimisation of the operation. The investigation was carried out in connection with pilot plant investigations at Damhusllen Wastewater Treatment Plant in order to establish the design basis for upgrading the treatment plants in the city of Copenhagen. Calibration of the model was done with thorough characterisation of the wastewater and the activated sludge as the primary calibration tool. Special attention was paid to the nitrification process, which by previous investigations was shown to be occasionally inhibited. Model constants for the nitrification process were detennined from experiments. Default constants were used for nearly all other constants. The pilot plant was optimized with the calibrated model. Different operational strategies for improvement of the denitrification process were tested. The denitrification process was operated relatively poorly at the time for the optimisation. The calibration showed that it was possible to calibrate the model using the characterization of the wastewater and the activated sludge as the primary calibration tool. Further it was shown that the calihrated model could be used as a tool for optimising the operation of the pilot plant. The suggested operation correlated well with the practical realisable operation.
A newly developed simulation programme, based on the Activated Sludge Model No. 1, was used to investigate the model's abilities to predict variations in a Bio-Denipho pilot plant. The model was tested under both normal conditions and in connection with an inhibition incident on the pilot plant with positive results.
Pilot plant experiments have been performed over a period of four years in order to establish an experimental basis for the upgrading of the treatment plants of the city of Copenhagen to nitrogen removal. The design chosen is based on the alternating mode of operation. Nitrification rates have been determined in batch tests on activated sludge extracted from the pilot plants and through the measuring of transient concentrations during the alternating mode of operation in the aerobic reactor. The data have been nonnalised to standard conditions by correcting them according to the kinetic theory. By monitoring the normalised nitrification rate it could be established that the nitrification process was occasionally inhibited. The aerobic sludge age required to maintain nitrification has been estimated. A specific evaluation has been made of the sensitivity of the required sludge age to the oxygen concentration and temperature.
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