Abstract:In order to achieve process intensification for adsorption chillers and heat pumps, a new composite material was developed based on sintered aluminum fibers from a melt-extraction process and a dense layer of silico-aluminophosphate (SAPO-34) on the fiber surfaces. The SAPO-34 layer was obtained through a partial support transformation (PST) process. Preparation of a composite sample is described and its characteristic pore size distribution and heat conductivity are presented. Water adsorption data obtained under conditions of a large pressure jump are given. In the next step, preparation of the composite was scaled up to larger samples which were fixed on a small adsorption heat exchanger. Adsorption measurements on this heat exchanger element that confirm the achieved process intensification are presented. The specific cooling power for the adsorption step per volume of composite is found to exceed 500 kW/m 3 under specified conditions.
OPEN ACCESSEnergies 2015, 8 8432
Cellular metals based on iron have been intensively investigated during the last two decades. Because of the significant decrease in of the structural density of iron based cellular structures, numerous technologies have been developed for their manufacturing. Besides the tremendous weight reduction a combination with other properties like energy and noise absorption, heat insulation and mechanical damping can be achieved. This contribution will give an overview about the latest state in iron based cellular materials, including technologies in manufacturing, properties and potential applications.
The obvious advantages of metallic hollow sphere materials have lead to several attempts to produce such structures. None of these approaches has gained practical significance owing to the very high cost of the methods. A new powder metallurgical process using styrofoam spheres allows for the production of hollow spheres from arbitrary metals and alloys. The IFAM Department of Powder Metallurgy and Composite Materials, Dresden, has developed this process and added a method that produces random hollow sphere structures (RHS) directly from the green spheres.
Magnesium alloys offer excellent properties with regard to application as degradable implant. For bone implants, it is often desirable to use porous materials. However, the preparation of high-porosity magnesium implants has been difficult so far. The present study uses melt extracted magnesium fibers as the starting material for the sintering of highly porous magnesium bodies, i.e., from alloys MgY4 (W4) and MgY2Zn1CaMn (WZ21). Single short fibers of these alloys with an equivalent diameter between 100 and 250 mm and a length of 4-8 mm are manufactured by melt extraction. Thermodynamic calculations are used to determine the best conditions for liquid phase sintering of these Mg alloys. As no organic or other substances are needed in the process, it is possible to obtain high-purity, high-porosity (up to 75%) bodies with exclusively open porosity. Metallographic studies as well as mechanical and corrosion testing experiments complete this work.
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