In this work, Ag doped nano TiO 2 photocatalysts were synthesized in powder form by hydrothermal method at 180 ºC in 120 min. using different reduction agents. The synthesized powders were characterized by powder X-ray diffraction (XRD), Energy-dispersive X-ray spectroscopy (EDS), Surface area measurements (BET), Transmission electron microscopy (TEM) and scanning electron microscopy (SEM) analyses. The effect of reduction agents on the morphological properties of Ag doped nano TiO 2 has been studied. We have been observed that the use of different reduction agents affects the particle size and surface area. Ag doped nano TiO 2 photocatalysts were coated to the ceramic pellets by dip coating technique for photocatalytic study. Photocatalytic properties of the synthesized powder were examined in a circulating aquarium filled with indigo blue (IB) solution under UV irradiation. Periodical UV spectrophotometric analysis showed that indigo blue (IB) has been degraded and its concentration has decreased under UV irradiation by time.
Hydroxyapatite (HA) coatings have been used to improve biological and mechanical fixation of metallic prosthesis. Because of extraordinary features of carbon nanotubes (CNTs), they have a lot of facilities, such as extremely strong nanoreinforcement materials for composites. HA powders were synthesized and mixed with multiwalled carbon nanotubes (MWCNTs) by a hydrothermal process. Calcium acetate (Ca (CH(3)COO)(2)) and phosphoric acid (H(3)PO(4)) were used as starting materials for synthesizing nano-HA powders. HA-MWCNTs were treated together hydrothermally at 200 °C for 2 h to synthesize nano-HA powders mixed homogeneously with MWCNTs. Cathodic deposits were obtained on Ti-based alloys using suspensions containing nano-HA and MWCNTs dispersed in n-butanol solvent. It was shown that MWCNTs interacted with HA powders during hydrothermal processing, and therefore, they can easily be dispersed within aqueous-based suspensions. It was also shown that hydrothermal surface modification of MWCNTs with functional groups was achievable, which was a significant step toward eliminating nonwetting surface behavior of MWCNTs, resulting in obtaining homogeneous dispersion of them in liquids.
New metal-free and metallophthalocyanine compounds (Zn, Co, Ni, and Cu) were synthesized using 2-hydroxymethyl-1,4-benzodioxan and 4-nitrophthalonitrile compounds. All newly synthesized compounds were characterized by elemental analysis, FT-IR, UV-Vis, 1 H-NMR, MALDI-TOF MS, and GC-MS techniques. The applications of synthesized compounds in Schottky barrier diodes were investigated. Ag/Pc/p-Si structures were fabricated and charge transport mechanism in these devices was investigated using dc technique. It was observed from the analysis of the experimental results that the charge transport can be described by Ohmic conduction at low values of the reverse bias. On the other hand, the voltage dependence of the measured current for high values of the applied reverse bias indicated that space charge limited conduction is the dominant mechanism responsible for dc conduction. From the observed voltage dependence of the current density under forward bias conditions, it has been concluded that the charge transport is dominated by Poole-Frenkel emission.
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