Die Reaktion von (C6H5)2PbJ2 (I) in flüss. NH3 mit KNH2 führt zu K2[Pb(NH2)6] (II). Als Zwischenprodukte wurden isoliert: (C6H5)2PbJ2 · 3NH3 (III), (C6H5)2 · PbNH (V) und K2[(C6H5)2Pb(NH2)4] (VIII).
Die Stannane (I) reagierten mit K‐amid in flüssigem Ammoniak unter Abspaltung des jeweiligen Kohlenwasserstoffrestes zum K‐hexamido‐(II) und K‐triamidostannat (III).
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