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We present the second realization of the International Celestial Reference Frame (ICRF2) at radio wavelengths using nearly 30 years of Very Long Baseline Interferometry observations. ICRF2 contains precise positions of 3414 compact radio astronomical objects and has a positional noise floor of ∼40 μas and a directional stability of the frame axes of ∼10 μas. A set of 295 new "defining" sources was selected on the basis of positional stability and the lack of extensive intrinsic source structure. The positional stability of these 295 defining sources and their more uniform sky distribution eliminates the two greatest weaknesses of the first realization of the International Celestial Reference Frame (ICRF1). Alignment of ICRF2 with the International Celestial Reference System was made using 138 positionally stable sources common to both ICRF2 and ICRF1. The resulting ICRF2 was adopted by the International Astronomical Union as the new fundamental celestial reference frame, replacing ICRF1 as of 2010 January 1.

Interferometry at radio frequencies between Earth-based receivers separated by intercontinental distances has made significant contributions to astrometry and geophysics during the past three decades. Analyses of such very long baseline interferometric (VLBI) experiments now permit measurements of relative positions of points on the Earth's surface and of angles between celestial objects at levels of better than one cm and one nanoradian, respectively. The relative angular positions of extragalactic radio sources inferred from this technique presently form the best realization of an inertial reference frame. This review summarizes the current status of radio interferometric measurements for astrometric and geodetic applications. It emphasizes the theoretical models that are required to extract results from the VLBI observables at present accuracy levels. An unusually broad cross section of physics contributes to the required modeling. Both special and general relativity need to be considered in properly formulating the geometric part of the propagation delay. While high-altitude atmospheric charged-particle (ionospheric) effects are easily calibrated for measurements employing two well-separated frequencies, the contribution of the neutral atmosphere at lower altitudes is more difficult to remove. In fact, mismodeling of the troposphere remains the dominant error source. Plate tectonic motions of the observing stations need to be taken into account, as well as the nonpointlike intensity distributions of many sources. Numerous small periodic and quasiperiodic tidal effects also make important contributions to space geodetic observables at the centimeter level, and some of these are just beginning to be characterized. Another area of current rapid advances is the specification of the orientation of the Earth's spin axis in inertial space: nutation and precession. Highlights of the achievements of very long baseline interferometry are presented in four areas: reference frames, Earth orientation, atmospheric effects on microwave propagation, and relativity. The order-of-magnitude improvement of accuracy that was achieved during the last decade has provided essential input to geophysical models of the Earth's internal structure. Most aspects of VLBI modeling are also directly applicable to interpretation of other space geodetic measurements, such as active and passive ranging to Earth-orbiting satellites, interplanetary spacecraft, and the Moon. [S0034-6861(98)

The barrier potential to internal rotation in ethane is examined with bond-orbital wavefunctions. It is found that reasonable values of the barrier height are obtained over a wide range of bond polarities if the wavefunction is constrained to satisfy the Pauli exclusion principle. By contrast, for a Hartree product of local nonorthogonal bond orbitals, the barrier is very sensitive to bond polarity. On integration of the Hellmann–Feynman forces from the determinantal bond-orbital functions along a path that requires only force differences between staggered and eclipsed ethane, barrier values are calculated that closely parallel the corresponding total energy differences; use of an alternative path introduces a much larger error into the force calculation. The bond-function results are utilized to examine the question of error cancellation in barrier calculations and for a comparison with other studies of the ethane barrier. It is concluded that the dominant contribution to the barrier is the overlap (exclusion-principle) repulsion between closed-shell, localized C–H bond orbitals and that the direct electrostatic and dispersion force interaction between these orbitals is relatively unimportant.