A simple analytical model that allows designing one-dimensional photonic crystal based dye sensitized solar cells of optimized performance, accounting for the actual optical features of the device, is herein presented. Based on the theoretical description of the effect of coupling such Bragg mirrors to the light harvesting electrode, recently reported experimental values of the spectral dependence of incident photon to current conversion efficiency attained for such structures are fairly reproduced and rationalized. A thorough analysis of them in terms of the interplay between the effect of the electrode thickness and the characteristics of the Bragg reflection, such as intensity, spectral position, and width, is provided. Predictions on the maximum enhancement factors expected for realistic structures are also presented.
Abstract:We demonstrate the advantage of combining non-diffractive beam shapes and femtosecond bursts for volume laser processing of transparent materials. By re-distribution of the single laser pulse energy into several sub-pulses with 25 ns time delay, the energy deposition in the material can be enhanced significantly. Our combined experimental and theoretical analysis shows that in burst-mode detrimental defocusing by the laser generated plasma is reduced, and the non-diffractive beam shape prevails. At the same time, heat accumulation during the interaction with the burst leads to temperatures high enough to induce material melting and even in-volume cracks. In an exemplary case study, we demonstrate that the formation of these cracks can be controlled to allow high-speed and high-quality glass cutting.
We report the fabrication and the characterization of buried waveguide in As(2)S(3) glass. It is well known that the interaction of femtosecond pulses with this material at high laser repetition rates results in a mainly negative refractive index variation, due to heat accumulation effect. However, we show here that a helical translation of the sample parallel to the laser beam, allows the inscription of a core of positive refractive variation, with full control over its magnitude and diameter. An example demonstrating the high symmetry of the guided mode is given.
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