In this study, biodiesel, also known as fatty acid methyl ester (FAME), was synthesized from multi-stage frying waste soybean oil using chicken eggshell-derived CaO and potassium-impregnated K + -CaO heterogeneous catalysts. Potassium-impregnated catalysts (1.25% K + -CaO, 2.5% K + -CaO, and 5% K + -CaO) were developed by treating the calcined waste eggshell powder with KOH in different wt % ratios. The catalysts were characterized using FTIR, XRD, FESEM, EDS, BET, and particle size analysis techniques. Box–Behnken design-based optimization was exploited to optimize the reaction parameters. A maximum yield of 98.46%, calculated via 1 H NMR, was achieved following a 5% K + doping, 12:1 methanol to oil molar ratio, 3% catalyst amount, 180 min reaction time, and 65 °C reaction temperature. The catalyst (5% K + -CaO) responsible for maximum biodiesel production was found to be highly reusable, with a 30.42% conversion decrease in activity after eight cycles of reuse. Gas chromatography was used to determine the composition of FAME produced from different cycles of waste soybean oil. Physicochemical parameters of the synthesized biodiesel were found to be compatible with EN and ASTM standards. This study has shown that the waste eggshell-derived heterogeneous catalysts have significant catalytic activity at relatively low K + doping and catalyst loading leading to high biodiesel conversion.

With an ever-increasing population and unpredictable climate changes, meeting energy demands and maintaining a sustainable environment on Earth are two of the greatest challenges of the future. Biogas can be a very significant renewable source of energy that can be used worldwide. However, to make it usable, upgrading the gas by removing the unwanted components is a very crucial step. CO 2 being one of the major unwanted components and also being a major greenhouse gas must be removed efficiently. Different methods such as physical adsorption, cryogenic separation, membrane separation, and chemical absorption have been discussed in detail in this review because of their availability, economic value, and lower environmental footprint. Three chemical absorption methods, including alkanolamines, alkali solvents, and amino acid salt solutions, are discussed. Their primary works with simple chemicals along with the latest works with more complex chemicals and different mechanical processes, such as the DECAB process, are discussed and compared. These discussions provide valuable insights into how different processes vary and how one is more advantageous or disadvantageous than the others. However, the best method is yet to be found with further research. Overall, this review emphasizes the need for biogas upgrading, and it discusses different methods of carbon capture while doing that. Methods discussed here can be a basic foundation for future research in carbon capture and green chemistry. This review will enlighten the readers about scientific and technological challenges regarding carbon dioxide minimization in biogas technology.

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