rGO of QD-rGO nanocomposite could absorb and convert into heat when harvested under NIR radiation, resulting cell death with reduction of fluorescence.
Electricity demand is increasing, as a result of increasing consumers in the electricity market. By growing smart technologies such as smart grid and smart energy management systems, customers were given a chance to actively participate in demand response programs (DRPs), and reduce their electricity bills as a result. This study overviews the DRPs and their practices, along with home energy management systems (HEMS) and load management techniques. The paper provides brief literature on HEMS technologies and challenges. The paper is organized in a way to provide some technical information about DRPs and HEMS to help the reader understand different concepts about the smart grid, and be able to compare the essential concerns about the smart grid. The article includes a brief discussion about DRPs and their importance for the future of energy management systems. It is followed by brief literature about smart grids and HEMS, and a home energy management system strategy is also discussed in detail. The literature shows that storage devices have a huge impact on the efficiency and performance of energy management system strategies.
Particular interest has been given to the self-organized titania nanotube TiO 2 thin films prepared by using anodisation method followed by annealing in the air, while the CdSe layer was potentiostatically electrodeposited onto the TiO 2 nanotube films at various pH. The resulting films were studied by using energy dispersive X-ray spectroscopy, X-ray diffraction, field emission scanning electron microscopy, UV-Vis spectroscopy and photoelectrochemical analysis to characterize their compositional, crystalline structure, surface morphological, optical, and photoconversion efficiency characteristics. The resulting CdSe/TiO 2 nanotube exhibits significant enhancement in optical absorption, photocurrent density and photoconversion efficiency. CdSe/TiO 2 nanotube prepared at pH 3 exhibited the highest photocurrent density of 2.13 mA cm −2 and photoconversion efficiency of 1.02 % which is 51 times higher than TiO 2 nanotube array. This may due to the formation of CdSe nanocrystals which were well crystallized and bonded with TiO 2 NTAs contributing to the enhanced photoresponse and photostability of the overall performance of CdSe/TiO 2 NTAs heterostructures.
Highly ordered titania nanotubes (TNTs) were synthesised by an electrochemical anodization method for supercapacitor applications. However, the capacitive performance of the TNTs was relatively low and comparable to the conventional capacitor. Therefore, in order to improve the capacitive performance of the TNTs, a fast and facile electrochemical reduction method was applied to modify the TNTs (R-TNTs) by introducing oxygen vacancies into the lattice. X-ray photoelectron spectroscopy (XPS) data confirmed the presence of oxygen vacancies in the R-TNTs lattice upon the reduction of Ti 4+ to Ti 3+ . Electrochemical reduction parameters such as applied voltage and reduction time were varied to optimize the best conditions for the modification process. The electrochemical performance of the samples was analyzed in a three-electrode configuration cell. The cyclic voltammogram recorded at 200 mV s −1 showed a perfect square-shaped voltammogram indicating the excellent electrochemical performance of R-TNTs prepared at 5 V for 30 s. The total area of the R-TNTs voltammogram was 3 times larger than the unmodified TNTs. A specific capacitance of 11.12 mF cm −2 at a current density of 20 A cm −2 was obtained from constant current charge-discharge measurements, which was approximately 57 times higher than that of unmodified TNTs. R-TNTs also displayed outstanding cycle stability with 99% capacity retention after 1000 cycles.
Mn2O3 was coated onto reduced titania nanotubes by reverse pulse electrodeposition, showing smooth and homogenous deposits without covering the opening of the nanotubes.
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