A triaxial LiFePO4 nanowire with a multi wall carbon nanotube (VGCF:Vapor-grown carbon fiber) core column and an outer shell of amorphous carbon was successfully synthesized through the electrospinning method. The carbon nanotube core oriented in the direction of the wire played an important role in the conduction of electrons during the charge-discharge process, whereas the outer amorphous carbon shell suppressed the oxidation of Fe2+. An electrode with uniformly dispersed carbon and active materials was easily fabricated via a single process by heating after the electrospinning method is applied. Mossbauer spectroscopy for the nanowire showed a broadening of the line width, indicating a disordered coordination environment of the Fe ion near the surface. The electrospinning method was proven to be suitable for the fabrication of a triaxial nanostructure.
Visual Reaction Time (RT) was measured by presenting three different sizes of stimulus to the central and peripheral fields of vision in 6 soccer players and 6 nonathletes. An electromyogram was recorded from the flexor digitorum superficialis muscle of the responding forearm. Peripheral visual RT was longer in comparison to central visual RT due to an increment in Premotor Time. The soccer players showed shorter Premotor Times during central and peripheral visual RT tasks than nonathletes, suggesting that the soccer players are better able to respond quickly to a stimulus presented to peripheral as well as central positions.
The present study examined whether EMG-RT (RT) for a key press to stimulus in peripheral and central visual fields decreases with practice. 16 male students were divided into two groups, one practicing using peripheral vision, the other practicing using central vision. Before and after practice, RT was measured for peripheral and central visual fields. Each group practiced three blocks of 25 trials five days a week for three weeks. RT for peripheral and central visual fields decreased with practice. Practice effects on RT for the peripheral visual field extended to RT for the central visual field, and vice versa. It is suggested that the transfer may reflect the decrease in the central nervous system's processing time in common between two RT tasks.
The aims of this study were (1) to evaluate changes in muscle activity associated with physiological fatigue and decreased swimming velocity (SV) during 200 m of front crawl swimming, and (2) to examine the relationship between the decreased SV and changes in kinematic or electromyogram parameters. Twenty swimmers participated in a 4 × 50-m swim test. The surface EMG of 11 muscles (7 in the upper limbs and 4 in the lower limbs) was measured and the mean amplitude value (MAV) for one stroke cycle was obtained. The SV and arm angular velocity (AAV) of shoulder flexion during the first (early stroke) and second (late stroke) half of the underwater arm stroke were analyzed using an underwater camera. The AAV, the MAV of flexor carpi ulnaris (FCU), biceps brachii (BB), and triceps brachii during the early stroke, and the MAV of rectus femoris decreased along with a decrease in SV. In contrast, the MAV of the pectoralis major (PM) increased significantly in the final 50 m. The rate of change in MAVs (ΔMAVs) of FCU, BB and latissimus dorsi during the early stroke, and ΔMAV of biceps femoris were significantly correlated with ΔSV and/or ΔAAV. Positive correlations were identified between ΔMAVs of several muscles. However, no negative correlations were observed between ΔMAVs. These results suggest that the decrease in SV was related to decreases in the activities of several muscles that coordinated with each other, and that a compensating strategy occurred between PM and other muscles in the final 50 m.
Iron mixed-valence complex, (n-C(3)H(7))(4)N[Fe(II)Fe(III)(dto)(3)](dto = C(2)O(2)S(2)), shows a spin entropy-driven phase transition called charge transfer phase transition in [Fe(II)Fe(III)(dto)(3)](-)(infinity) around 120 K and a ferromagnetic transition at 7 K. These phase transitions remarkably depend on the hexagonal ring size in the two-dimensional honeycomb network structure of [Fe(II)Fe(III)(dto)(3)](-)(infinity). In order to control the magnetic properties and the electronic state in the dto-bridged iron mixed-valence system by means of photoirradiation, we have synthesized a photosensitive organic-inorganic hybrid system, (SP)[Fe(II)Fe(III)(dto)(3)](SP = spiropyran), and investigated the photoinduced effect on the magnetic properties. Upon UV irradiation at 350 nm, a broad absorption band between 500 and 600 nm appears and continuously increases with the photoirradiation time, which implies that the UV irradiation changes the structure of spiropyran from the closed form to the open one in solid state. The photochromism in spiropyran changes the ferromagnetic transition temperature from 5 to 22 K and the coercive force from 1400 to 6000 Oe at 2 K. In this process, the concerted phenomenon coupled with the charge transfer phase transition in [Fe(II)Fe(III)(dto)(3)](-)(infinity) and the photoisomerization of spiropyran is realized.
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