A major objective for the single crystal diffraction instrument currently under construction at the Spallation Neutron Source (SNS), ORNL, is to make extensive use of beam transport and focusing optics. This time-of-flight Laue diffractometer will implement a super mirror beam guide following the trace of a parabolic curve in a piecewise approximation [1]. In this context micro-focusing optics under development for neutron scattering applications are also being reviewed and recently collected data from prototypical assemblies and setups are being presented. For a number of years we have been employing single-crystal neutron diffraction to investigate structures of sigma complexes of transition metals. Sigma complexes are of special interest because they are ubiquitous intermediates in metal-catalyzed reactions including hydrogenations, activation and functionalization of hydrocarbons, and hydroborations. Here we will report on some recent results obtained using the SCD instrument at Argonne's Intense Pulsed Neutron Source, which has been upgraded with two new position-sensitive Anger detectors to achieve increased data collection efficiency. In the future, we hope to be able to dramatically extend these studies at the Spallation Neutron Source (SNS) using the singlecrystal diffractometer (Topaz) A state-of-art semiconductor technology based area X-ray detector, namely D/teX-25, has recently been developed. This detector has ultra high-sensitivity and can achieve ultra high-speed X-ray diffraction (XRD) measurement up to a maximum speed of a pattern of 160º2 in one minute or 90º2 in about 30 seconds, which is more than 30 times faster than a conventional speed of 5º2 per minute with a scintillation or a proportional counter. In addition to high-speed data acquisition, the D/teX-25 can provide X-ray diffraction analysis with areal resolution for the study of sample uniformity and the possible presence of large or aggregated particles in a specimen. Thus the D/teX-25 detector is useful for dynamic in-situ studies of various materials. Some examples of fast and/or two dimensional XRD measurements with a D/teX-25 detector will be given. Image plates (IPs) allow high-resolution, high-dynamic range registration of multiple datasets on a single IP. When refining accurate lattice parameters, independent determination of strongly correlated parameters, usually displacement and zero offset, is essential. We have investigated the use of embedded radioactive fiducial markers to absolutely calibrate the angular scale on each IP and thereby eliminate the need to refine zero offset.We found that a random rotation of up to +/-0.3 degrees is introduced in our BAS2000 scanner during loading of the IP. The consequent systematic variation in refined lattice parameter for multiple datasets on a single image plate seriously complicates diffraction-based thermometry. Typical variation in refined lattice parameter for data collected under identical conditions at each extremity of the IP was found to be 0.02% for uncorrected data, and 0...
A programming environment for the multi-processor system -HD-Picot Systemhas been developed. HD-Picot System is a programmable real-time video signal processing system. It has an architecture suitable for video-rate processing of signals, including both conventional TV and high definition TV.The programming environment transforms a video processing application written in graphical form into code sets executable on HD-Picot System. It consists mainly of a graphical editor and an integrated compiler which breaks up a signal flow graph, compensates timing differences between signal paths, generates programs, and displays control panel on a screen of a workstation.
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