Deterioration of the urban thermal environment, especially in megacities with intensive populations and high densities of impervious surfaces, is a global issue resulting from rapid urbanization. The effects of landscape patterns on the urban thermal environment within a single area or single period have been well documented. Few studies, however, have explored whether the effects can be adapted to various cities at different urbanization stages. This paper investigated the variations of these effects in the five largest and highly urbanized megacities of China from 1990 to 2020 using various geospatial approaches, including concentric buffer analysis, correlation analysis, and hierarchical ridge regression models. The results indicated that the effects of landscape patterns on the urban thermal environment were greatly variable at different urbanization stages. Although landscape composition was more important than landscape configuration in determining the urban thermal environment, the standard coefficients of composition metrics continuously decreased from 1990 to 2020. However, configuration metrics, such as patch density, edge density, and shape complexity, could affect the land surface temperature (LST) to a larger extent at the highly urbanized stage. The urbanization process could also affect the cooling effect of urban green space. At the initial stage of rapid urban expansion in approximately 2000, urban green space explained the most variation in LST, with a value as high as 10%. To maximize the cooling effect, the spatial arrangement of urban green space should be highlighted in the region that was 10–15 km from the city center, where the mean LST experienced a significant decline. These results may provide deeper insights into improving the urban thermal environment by targeted strategies in optimizing landscape patterns for areas at different urbanization stages.
A nickel-catalyzed highly regioselective
addition/cyclization of
ynamide-benzylnitriles with organoboronic acids has been developed.
The reaction offers an attractive route for the construction of diamino-functionalized
1-arylnaphthalenes, which is difficult to synthesize by other methods.
In addition, a wide range of functional groups are tolerated in this
reaction.
An efficient nickel(0)-catalyzed addition of benzyl nitriles to terminal vinyl ketones via C(sp 3 )−H functionalization has been developed. The reaction provides a novel and efficient protocol for the synthesis of α-functionalized benzyl nitriles with a wide range of structural diversity under mild reaction conditions while obviating the use of a strong base. The work might be potentially useful toward the development of an enantioselective variant using chiral nitrogen ligands.
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