Rechargeable aprotic Li–O2 batteries are one of the most promising next‐generation battery technologies that can deliver extremely high energy density. In the past decades, this technology has attracted worldwide attention, and considerable progress has been achieved. However, numerous critical scientific challenges remain to be solved for practical applications. A specific discussion of recent progress from the perspective of the stable aprotic Li–O2 system with high energy efficiency is presented. The discussion is highlighted on the reaction mechanisms on air cathode, stability of cell components in semi‐open surroundings, and improvement of battery performance by catalyst design. Challenges and perspectives are also presented. This study provides an intensive understanding of aprotic Li–O2 batteries and offers an important guideline for developing reversible and high‐efficiency Li–O2 batteries.

In this paper, we combine experimental dark-field scattering spectroscopy and accurate electrodynamics calculations to investigate the scattering properties of two-dimensional plasmonic lattices based on the concept of aperiodic order. In particular, by discussing visible light scattering from periodic, Fibonacci, Thue-Morse and Rudin-Shapiro lattices fabricated by electron-beam lithography on transparent quartz substrates, we demonstrate that deterministic aperiodic Au nanoparticle arrays give rise to broad plasmonic resonances spanning the entire visible spectrum. In addition, we show that far-field diffractive coupling is responsible for the formation of characteristic photonic-plasmonic scattering modes in aperiodic arrays of metal nanoparticles. Accurate scattering simulations based on the generalized Mie theory approach support our experimental results. The possibility of engineering complex metal nanoparticle arrays with distinctive plasmonic resonances extending across the entire visible spectrum can have a significant impact on the design and fabrication of novel nanodevices based on broadband plasmonic enhancement.

We present a wavelength-tunable, compact, high speed and low power silicon microring modulator. With a ring radius of 5 microm, we demonstrate a modulator with a high speed of 12.5 Gbps and a driving voltage of 3 V to achieve approximately 6 dB extinction ratio in high speed measurement. More importantly, tunability of the resonant wavelength is accomplished by means of a microheater on top of the ring, with an efficiency of 2.4 mW/nm (2.4 mW is needed to tune the resonant wavelength by 1 nm). This device aims to solve the narrow bandwidth problem of silicon microcavity modulators and increase the data bandwidth in optical interconnect systems.

We experimentally demonstrate the optical transmission at 1550 nm of the fundamental slot modes (quasi-TM modes) in horizontal single and multiple slot waveguides and ring resonators consisting of deposited amorphous silicon and silicon dioxide. We demonstrate that the horizontal multiple slot configuration provides enhanced optical confinement in low index slot regions compared to a horizontal single slot structure with the same total SiO2 layer thickness by comparing their thermo-optic coefficients for the horizontal slot ring resonators. We show in these early structures that horizontal slot waveguides have low propagation loss of 6 approximately 7 dB/cm. The waveguide loss is mainly due to a-Si material absorption. The addition of a-Si/SiO(2) interfaces does not introduce significant scattering loss in a horizontal multiple slot waveguide compared to a horizontal single slot waveguide.

We present thermally reconfigurable multiplexing devices based on silicon microring resonators with low tuning power and low thermal crosstalk. Micro-heaters on top of the rings are employed to tune the resonant wavelengths through the thermo-optic effect of silicon. We achieve a low tuning power of 21 mW per free spectral range for a single ring by exploiting thermal isolation trenches close to the ring waveguides. Negligible thermal crosstalk is demonstrated for rings spaced by 15 microm, enabling compact multiplexing devices. The tuning time constant is demonstrated to be less than 10 micros.

The in situ structural evolution of the catalyst was successfully achieved by in situ electrochemical dealloying approach. Direct evidence of O–O bond formation was probed by operando ATR FT-IR, suggesting the direct O2 evolution mechanism.

We demonstrate a compact waveguide-based high-speed Ge electro-absorption (EA) modulator integrated with a single mode 3 µm silicon-on-isolator (SOI) waveguide. The Ge EA modulator is based on a horizontally-oriented p-i-n structure butt-coupled with a deep-etched silicon waveguide, which transitions adiabatically to a shallow-etched single mode large core SOI waveguide. The demonstrated device has a compact active region of 1.0 × 45 µm(2), a total insertion loss of 2.5-5 dB and an extinction ratio of 4-7.5 dB over a wavelength range of 1610-1640 nm with -4V(pp) bias. The estimated Δα/α value is in the range of 2-3.3. The 3 dB bandwidth measurements show that the device is capable of operating at more than 30 GHz. Clear eye-diagram openings at 12.5 Gbps demonstrates large signal modulation at high transmission rate.

We show that by using a suitable soluble redox mediator, the charging overpotential can be reduced and the round-trip efficiency can be improved in an aprotic Li-O2 battery. Not only do we explore a new redox couple, 10-methyl-10H-phenothiazine, as a soluble catalyst that improves the electrochemical performance, but we also propose possible challenges that need to be overcome for the future improvement of aprotic Li-O2 batteries.