Colloidal suspensions of Na-fluorohectorite synthetic clay platelets in saline water exhibit coexisting isotropic and nematic phases, due to gravitational separation of the polydisperse particles. We study the ordering of the platelets at the interfaces between various coexisting phases. Four different experimental techniques are employed: visual observation of birefringence, synchrotron wide angle and small-angle X-ray scattering, and magnetic resonance imaging. We find that at the narrow isotropic sol-nematic sol interface the platelets are lying horizontally, i.e. with their mean platelet normal along the vertical direction. The experiments indicate that the platelets align homeotropically both at the isotropic sol-nematic sol interface and at the nematic sol-wall interface. We further investigate the complex alignment effect of a horizontally applied magnetic field in the nematic sol, and we compare it with the adjacent nematic gel.

We have studied stable strata of gravity-induced phase separation in suspensions of synthetic Na-fluorohectorite clay in saline solutions. We have observed how the strata depend on clay concentration as well as on salt content. The mass distribution and density variation at the isotropic-nematic interface indicate that existing models and assumptions in existing simulations are able to relatively well account for the observed behavior. We suggest that discrepancies could be due to the high polydispersity and the irregular shape of our Na-fluorohectorite particles, as well as diffusive double-layer effects, which could result in a competition between nematic ordering and gelation. The dependence on ionic strength displays three main regimes irrespective of clay concentration. At low ionic strength (approximately 0.1-5 mM NaCl), the Debye screening length is longer than the van der Waals force range. In this regime, the particles repel each other electrostatically and entropy-driven Onsager-type nematic ordering may occur, although gelation effects could also play a role. For ionic strengths above about 5 mM, we believe that the van der Waals force comes into play and that particles attract each other locally according to the classical Derjaguin, Landau, Verwey, and Overbeek (DLVO) model of colloid interactions, resulting in a small-domain regime of attractive nematiclike ordering. In the third regime, for ionic strengths above approximately 10 mM, the clay particles aggregate into larger assemblies, due to the dominant van der Waals force, and the observed birefringency is reduced. We have studied the nematic phase in detail between crossed polarizers and have found textures showing nematic Schlieren patterns. By rotating the polarizers as well as the samples, we have observed examples of disclinations of strengths -1, -1/2, and +1.